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2차 버퍼층 ZnMgO 박막의 Mg/(Mg+Zn) 비율 조절을 통한 SnS 박막 태양전지 효율 향상 KCI 등재 SCOPUS

Improving the Efficiency of SnS Thin Film Solar Cells by Adjusting the Mg/(Mg+Zn) Ratio of Secondary Buffer Layer ZnMgO Thin Film

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한국재료학회지 (Korean Journal of Materials Research)
한국재료학회 (Materials Research Society Of Korea)
초록

In the recent years, thin film solar cells (TFSCs) have emerged as a viable replacement for crystalline silicon solar cells and offer a variety of choices, particularly in terms of synthesis processes and substrates (rigid or flexible, metal or insulator). Among the thin-film absorber materials, SnS has great potential for the manufacturing of low-cost TFSCs due to its suitable optical and electrical properties, non-toxic nature, and earth abundancy. However, the efficiency of SnS-based solar cells is found to be in the range of 1 ~ 4 % and remains far below those of CdTe-, CIGS-, and CZTSSe-based TFSCs. Aside from the improvement in the physical properties of absorber layer, enormous efforts have been focused on the development of suitable buffer layer for SnS-based solar cells. Herein, we investigate the device performance of SnS-based TFSCs by introducing double buffer layers, in which CdS is applied as first buffer layer and ZnMgO films is employed as second buffer layer. The effect of the composition ratio (Mg/(Mg+Zn)) of RF sputtered ZnMgO films on the device performance is studied. The structural and optical properties of ZnMgO films with various Mg/(Mg+Zn) ratios are also analyzed systemically. The fabricated SnS-based TFSCs with device structure of SLG/Mo/SnS/CdS/ZnMgO/AZO/Al exhibit a highest cell efficiency of 1.84 % along with open-circuit voltage of 0.302 V, short-circuit current density of 13.55 mA cm−2, and fill factor of 0.45 with an optimum Mg/(Mg + Zn) ratio of 0.02.

목차
Abstract
1.서 론
2. 실험방법
    2.1 ZnMgO 박막 제작
    2.2 SnS 박막 태양전지 제작 및 특성평가
3. 결과 및 고찰
4.결 론
References
저자
  • 이효석(전남대학교 광전자융합기술연구소 신소재공학과) | Hyo Seok Lee (Department of Materials Science and Engineering, and Optoelectronic Convergence Research Center, Chonnam National University)
  • 조재유(전남대학교 광전자융합기술연구소 신소재공학과) | Jae Yu Cho (Department of Materials Science and Engineering, and Optoelectronic Convergence Research Center, Chonnam National University)
  • 윤성민(한국생산기술연구원 스마트에너지나노융합연구그룹) | Sung-Min Youn (Korea Institute of Industrial Technology)
  • 정채환(한국생산기술연구원 스마트에너지나노융합연구그룹) | Chaehwan Jeong (Korea Institute of Industrial Technology)
  • 허재영(전남대학교 광전자융합기술연구소 신소재공학과) | Jaeyeong Heo (Department of Materials Science and Engineering, and Optoelectronic Convergence Research Center, Chonnam National University) Corresponding author