Black carbon (BC), which is mainly contained in fine particulate matters, is one of the typical anthropogenic air pollutants that are generated from the incomplete combustion process and discharged into the atmosphere, and its various health effects particularly on children have been a growing concern. In this study, BC and particulate matters were closely analyzed in an elementary school adjacent to a high- traffic road in a large metropolitan city. The investigation showed that black carbon behaved similarly to ultrafine dust of 0.3 μm or less in the air, accounting for 20%-40% of it. The occurrence of high concentration outdoor pollution influences the BC content in indoor particulate matters. The average I/O value was 0.7 during the class-hours, and 0.8 without students. However, when students played in the classroom, the range of BC concentrations varied from 0.25 to 1.15, wider than 0.41-1.13 without students. Although this study was conducted with regard to just one elementary school, it can be considered to represent the typical air quality status of domestic schools, and it is believed to present valuable data which can be utilized to assist with preparing measures to enhance the air quality management of schools.