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Giant‑miscanthus‑derived activated carbon and its application to lithium sulfur batteries KCI 등재

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Carbon Letters (Carbon letters)
한국탄소학회 (Korean Carbon Society)
초록

Giant miscanthus (GM) is an Asian grass that can produce biomass in high yields per land area. It can be used as a cathode material in lithium sulfur (Li/S) batteries. Giant-miscanthus-derived activated carbon (GMAC) is prepared via carbonization of GM followed by KOH activation. It is prepared with a large amount of KOH, and thus contained more defects but had a highly porous structure and graphitic cluster lattice. GMAC has a large specific surface area of 3327 m2/g and a large total pore volume of 1.86 cm3/g. The pore volume served as a storage space for the retention of polysulfides, thereby inhibiting the shuttle effect. When a GMAC–sulfur composite cathode is tested in a Li/S battery, an initial discharge capacity of 1148 mAh/g can be attained at 0.1 C. In a cyclic charge–discharge experiment at 1 C, discharge capacities of 529 mAh/g and 248 mAh/g are observed in the first and 200th cycles, respectively.

목차
    Abstract
    1 Introduction
    2 Experimental
        2.1 Synthesis of giant-miscanthus-derived activated carbons
        2.2 Preparation of activated carbon–sulfur composites
        2.3 Electrochemical measurements
        2.4 Characterization of the materials
    3 Results and discussion
    4 Conclusion
    Acknowledgements 
    References
저자
  • Geon Hae Lim(Energy Storage Materials Center, Korea Institute of Ceramic Engineering and Technology)
  • Ji Su Chae(Energy Storage Materials Center, Korea Institute of Ceramic Engineering and Technology)
  • Young‑Lok Cha(Bioenergy Crop Research Center, NICS, RDA, 293‑5 Cheongcheon)
  • Yun Chan Kang(Department of Materials Science and Engineering, Korea University)
  • Kwang Chul Roh(Energy Storage Materials Center, Korea Institute of Ceramic Engineering and Technology)