This work reveals a modified method for the preparation of activated carbon (P-ACA) using low-cost materials (mix natural asphalt: polypropylene waste). The P-ACA was prepared at 600 °C by assisting KOH and HF. The morphological variations and chemical species of the P-ACA were characterized using SEM–EDX and FTIR. The active surface area, density and ash content of the P-ACA were also investigated. Adsorption properties of P-ACA were used for the thermodynamic and kinetic study of 4-((2-hydroxy naphthalenyl) diazenyl) antipyrine (HNDA), which was prepared as a novel azo dye in this work. The optimal conditions (initial concentration, adsorbent dose, contact time and temperature) of the adsorption process were determined. Adsorption isotherms (Freundlich and Langmuir) were applied to the experimental data. These isothermal constants were used to describe the nature of the adsorption system, and the type of interaction between the dye and the P-ACA surface. The results have indicated that the mixture (Natural asphalt-polypropylene waste) is efficient for the synthesis of P-ACA. The synthesized P-ACA demonstrates the presence of pores on the surface with various diameter ranges (from 1.4 to 4.5 μm). Furthermore, P-ACA exhibits an active surface area of 1230 m2 g−1, and shows a high adsorption capacity for HNDA.

    Abstract
    1 Introduction
    2 Experimental
        2.1 Materials
        2.2 Modification of rheological properties of Asphalt using polypropylene
        2.3 Preparation and characterization of P-ACA​
        2.4 Preparation of HNDA
        2.5 Preparation of stock solution
        2.6 Estimation of adsorbate
        2.7 Adsorption isotherms
        2.8 Determination of the thermodynamic functions
    3 Results and discussion
        3.1 Characterization of P-ACA​
        3.2 Characterization of HNDA
        3.3 Thermodynamic study of HNDA adsorption on P-ACA​
        3.4 Calculation of thermodynamic functions for adsorption process
        3.5 Adsorption isotherms
        3.6 Adsorption kinetics
    4 Conclusion
    References

• Homam T. S. AL‑Sayd Toohi(Department of Medical Laboratory Technique, Al-Hadba’a University College)
• Muwafaq Ayesh Rabeea(Department of Applied Chemistry, College of Applied Sciences‑Hit, University Of Anbar)
• Jasim Ali Abdullah(Department of Chemistry, College of Education for Pure and Science, University of Mosul)
• Rasim Farraj Muslim(Department of Environmental Sciences, College of Applied Sciences‑Hit, University Of Anbar)