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Triazine‑based 2D covalent organic framework‑derived nitrogen‑doped porous carbon for supercapacitor electrode KCI 등재

  • 언어ENG
  • URLhttps://db.koreascholar.com/Article/Detail/420673
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Carbon Letters (Carbon letters)
한국탄소학회 (Korean Carbon Society)
초록

Doped porous carbon materials have attracted great interest owing to their excellent electrochemical performance toward energy storage applications. In this report, we described the synthesis of nitrogen-doped porous carbon (N-PC) via carbonization of a triazine-based covalent organic framework (COF) synthesized by Friedel–Crafts reaction. The as-synthesized COF and N-PC were confirmed by X-ray diffraction. The N-PC exhibited many merits including high surface area (711 m2 g−1), porosity, uniform pore size, and surface wettability due to the heteroatom-containing lone pair of electron. The N-PC showed a high specific capacitance of 112 F g−1 at a current density of 1.0 A g−1 and excellent cyclic stability with 10.6% capacitance loss after 5000 cycles at a current density of 2.0 A g−1. These results revealed that the COF materials are desirable for future research on energy storage devices.

목차
    Abstract
    1 Introduction
    2 Experimental
        2.1 Materials
        2.2 Synthesis of triazine-based COF and N-PC
        2.3 Electrochemical measurements
        2.4 Characterization
    3 Results and discussion
    4 Conclusion
    Acknowledgements 
    References
저자
  • Stella Vargheese(Department of Nanoscience and Technology, Bharathiar University)
  • Muthu Dinesh(Department of Nanoscience and Technology, Bharathiar University)
  • K. V. Kavya(Department of Nanoscience and Technology, Bharathiar University)
  • Dhanaprabhu Pattappan(Department of Nanoscience and Technology, Bharathiar University)
  • Ramasamy Thangavelu Rajendra Kumar(Department of Nanoscience and Technology, Bharathiar University)
  • Yuvaraj Haldorai(Department of Nanoscience and Technology, Bharathiar University)