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Utilization of green alga Ulva lactuca for sustainable production of meso‑micro porous nano activated carbon for adsorption of Direct Red 23 dye from aquatic environment KCI 등재

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  • URLhttps://db.koreascholar.com/Article/Detail/420727
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Carbon Letters (Carbon letters)
한국탄소학회 (Korean Carbon Society)
초록

The production of macroalgae-derived adsorbent is of great importance to realize the idea of treating pollutants with invaluable renewable materials. Herein, a novel meso-micro porous nano-activated carbon was prepared from green alga Ulava lactuca in a facile way via chemical activation with zinc chloride. The resultant activated carbon possesses a significant specific surface area 1486.3 m2/ g. The resulting activated carbon was characterized and investigated for the adsorption of Direct Red 23 (DR23) dye from an aqueous environment. Batch method was conducted to study the effects of different adsorption processes on the DR23 dye adsorption from water. Isotherms and kinetics models were investigated for the adsorption process of DR23 dye. It was found that the adsorption data were well fitted by Langmuir model showing a monolayer adsorption capacity 149.26 mg/g. Kinetic experiments revealed that the adsorptions of DR23 dye can be described with pseudo-secondorder model showing a good correlation (R2 > 0.997). The prepared activated carbon from Ulava lactuca was exposed to a total of six regeneration experiments. The regeneration result proved that the fabricated activated carbon only loses 19% of its adsorption capacity after six cycles. These results clearly demonstrated the high ability of the obtained active carbon to absorb anionic dyes from the aqueous environment.

목차
    Abstract
    1 Introduction
    2 Materials and methods
        2.1 Materials
        2.2 Preparation of impregnated Ulva lactuca nano activated carbon (IUAC)
        2.3 Characterization of Ulva lactuca and IUAC​
        2.4 DR23 dye uptake experiments using batch method
        2.5 Adsorption isotherm
        2.6 Regeneration experiments
    3 Results and discussion
        3.1 Characterization of Ulva lactuca (UL) and IUAC​
        3.2 Effect of adsorption parameter
        3.3 Isotherm models
        3.4 Kinetic models
        3.5 Regeneration study of IUAC​
        3.6 Comparison of adsorption capability of IUAC with other adsorbents for DR23 dye.
    4 Conclusion
    References
저자
  • Ahmed El Nemr(Environmental Division, National Institute of Oceanography and Fisheries, NIOF, Kayet Bey, El‑Anfoushy, Alexandria, Egypt)
  • Amany G. M. Shoaib(Environmental Division, National Institute of Oceanography and Fisheries, NIOF, Kayet Bey, El‑Anfoushy, Alexandria, Egypt)
  • Amany El Sikaily(Environmental Division, National Institute of Oceanography and Fisheries, NIOF, Kayet Bey, El‑Anfoushy, Alexandria, Egypt)
  • Safaa Ragab(Environmental Division, National Institute of Oceanography and Fisheries, NIOF, Kayet Bey, El‑Anfoushy, Alexandria, Egypt)
  • Alaa El‑Deen A. Mohamed(Chemistry Department, Faculty of Science, Damanhur University)
  • Asaad F. Hassan(Chemistry Department, Faculty of Science, Damanhur University)