This paper mainly focuses on the maximum decay heat estimation generated from spent fuel assemblies in the spent fuel pool of Kori units 3&4 at the beginning decommissioning. It is assumed that the spent fuel pool is fully occupied with 2,260 spent fuel assemblies, same as its design capacity. In addition, equally 56.5 spent fuel assemblies have been generated per year. The minimum cooling time is five years considering the transition phase between the permanent shutdown and the amendment of Operating License for decommissioning. Sending and receiving of spent fuel assemblies to/from other units are neglected. Seven representative spent fuel assembly groups are established based on the burnup rate and cooling time. Conservatively high values for the burnup rates and low values for the cooling times are applied. Calculation of the decay heat of each representative group has been performed by using ORIGEN decay solver of SCALE. Then, total decay heat has been calculated based on this. Group 1, 2, and 3 contain comparatively old spent fuel assemblies with 45 GWd/tU burnup rate and 20~30 cooling years. The calculation shows 489~586 watts of decay heat per assembly. Group 4, 5, 6, and 7 contain comparatively new spent fuel assemblies with 55 GWd/tU burnup rate and 5~20 cooling years. The calculation shows 741~1,483 watts of decay heat per assembly. The total maximum decay heat therefore is estimated as 1,609,459 watts.