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Case Study on the Quantification of Residual Moisture in Dry Storage System
- 언어ENG
- URLhttps://db.koreascholar.com/Article/Detail/430407
p.115
To dry storage of spent nuclear fuel withdrawn the wet storage, all moisture inside the dry storage container must be removed to ensure the long-term integrity and retrievability. Substantial amounts of residual water in dry storage container may have potential impacts on the fuel, cladding, and other components in the dry storage system, such as fuel degradation and cladding corrosion, embrittlement, and breaching. The drying could perform as a vacuum drying process or a forced helium dehydration process. In NUREG-1536, the evacuation of most water contained within the canister is recommended a pressure of 0.4 kPa (3 torr) to be held in the canister for at least 30 minutes while isolated from active vacuum pumping as a measure of sufficient dryness in the canister. Monitoring the moisture content in gas removed from the canister is considered as a means of evaluating adequate dryness. Dew point monitoring and special techniques could be used to evaluate this adequacy. Various studies are continuing for quantitative evaluation of residual moisture inside the dry storage system. Andrawes proposed a methodology for determining trace water contents in gaseous mixtures, utilizing gas chromatography together with a helium ionization source. A microwave plasma source and emission spectrometry were utilized to determine trace amounts of bound water in solid samples using peak areas of atomic oxygen (O) and hydrogen (H) emissions. Bryans measured the gas samples taken from the High Burn-Up Demonstration Cask at three intervals: 5 hours, 5 days, and 12 days after the completion of drying and backfilling in the North Anna power Station. To measure water content, a Vaisala humidity probe was used. Final results indicated that the cask gas water content built up over 12 days to a value of 17,400 ppmv ±10%, equivalent to approximately 100 g of water within the entire cask gas phase. Tahiyats also proposed a methodology that involves a direct current (dc) driven plasma discharge and optical emission spectroscopy for detecting and quantifying water vapor in a flowing gas stream under both trace and high water vapor loading conditions. For detecting water vapor concentration, the emission from H at 656.2 nm was employed. The H emission is the red visible spectral line generated by a hydrogen atom when an electron falls from the third lowest to the second lowest energy level, this suggests that the normalized H intensity can be used as a marker for water vapor detection and quantification. Several of the attempts are continuing to quantify water contents in dry storage system. Lessons learned by Case studies would be provided insights into how to improve future measurements.
