논문 상세보기

Carbonation of Strontium Chloride by Solid-Solid Reaction After Evaporation of LiCl-KCl Eutectic

  • 언어ENG
  • URLhttps://db.koreascholar.com/Article/Detail/430978
모든 회원에게 무료로 제공됩니다.
한국방사성폐기물학회 학술논문요약집 (Abstracts of Proceedings of the Korean Radioactive Wasts Society)
한국방사성폐기물학회 (Korean Radioactive Waste Society)
초록

It has been investigated on the management of Strontium-90 in KAERI. It is needed to separate the solute from the salt solution for the recovery of strontium after the chlorination of the strontium oxide in molten salt. A vacuum distillation technology was used for the separation of strontium from the molten salt in our previous study. Strontium chloride was successfully carbonated by reactive distillation of SrCl2 – K2CO3 – LiCl – KCl system. In this study, it was tried to develop another route to recover strontium from the salt solution by a solid-solid reaction for avoiding the entrainment of product and the salt-K2CO3 reaction. Reactive distillation experiments were carried out for SrCl2 - K2CO3 – LiCl – KCl system. The carbonation temperature and pressure were 520°C and 0.8 bar. After the carbonation reaction, the temperature was elevated to 820°C to remove KCl from the reaction product. SrCO3 and KCl peaks were found in the XRD analysis of the residual product. It could be concluded that SrCl2 can be successfully carbonated after salt removal by the solid-solid reaction.

저자
  • Sang Woon Kwon(Korea Atomic Energy Research Institute (KAERI)) Corresponding author
  • Eunsoo Lee(Korea Atomic Energy Research Institute (KAERI))
  • Byungsuk Park(Korea Atomic Energy Research Institute (KAERI))
  • Joon Bo Shim(Korea Atomic Energy Research Institute (KAERI))
  • Chang Hwa Lee(Korea Atomic Energy Research Institute (KAERI))