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Morphological Observation of the Corrosion of Double Corrosion Resistant Barrier

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한국방사성폐기물학회 학술논문요약집 (Abstracts of Proceedings of the Korean Radioactive Wasts Society)
한국방사성폐기물학회 (Korean Radioactive Waste Society)
초록

In this study, a third metal layer with a higher corrosion potential than copper was introduced between the copper and cast iron layer to strengthen the corrosion resistance of the copper layer which is considered as a corrosion resistant barrier in the disposal container for spent nuclear fuel. Three types of corrosion-resistant metals, silver, nickel, and titanium, were selected as the intermediate insertion layer, and the galvanic specimens of two bonded metals were exposed to KURT (KAERI Underground Research Tunnel) groundwater and a high voltage of 1.0 V was applied to corrode the specimens at electrochemically accelerated condition. Corrosion of copper part was confirmed in Cu-Ti, Cu-Ni, and Cu-Ag galvanic specimens, but copper part was not corroded in Cu-Fe galvanic specimen. If the corrosion-resistant intermediate layer proposed in this study works properly, the local corrosion problem of copper disposal canister is expected to be some degree solved, which can apply to a welding part or a stress concentrated part.

저자
  • Minsoo Lee(Korea Atomic Energy Research Institute (KAERI)) Corresponding author
  • Junhyuk Jang(Korea Atomic Energy Research Institute (KAERI))
  • Jin-Seop Kim(Korea Atomic Energy Research Institute (KAERI))