The natural barrier system surrounding the geological repository for high-level radioactive waste plays a crucial role in preventing or delaying the leakage of radionuclides. Therefore, the natural barrier should ensure low permeability to prevent groundwater flow into the engineered barrier system throughout the repository’s lifetime. Crystalline rock, considered as the host rock for the geological repository in Korea, exhibits low intact rock permeability, but the crystalline rock often contains the multiple discontinuities due to its high brittleness that can allow the unexpected fluid flow. Therefore, the long-term hydraulic behavior of the discontinuity should be characterized while considering additional thermal, mechanical, and chemical effects. In comparison to thermal, hydraulic, and mechanical processes, the chemical processes on the discontinuities progress relatively slowly, resulting in limited researches to include these chemical processes. This research introduces mechanisms the involving coupled thermal-hydraulic-mechanicalchemical processes focusing on the rough fracture surfaces and asperities. The chemically-induced changes in mechanical and hydraulic properties are described based on pressure solution and precipitation concepts. A comprehensive review of laboratory tests, field tests, and numerical simulations is conducted related to the chemically-induced coupled processes in fractured rock. Laboratory tests, in particular, concentrate on microscopic changes in fracture asperities induced by pressure solution to analyze chemically-induced aperture changes. The TOUGHREACT, an integral finite difference method program for thermal-hydraulic-chemical simulations, is generally employed to model the chemical response of pressure solution and precipitation on fracture surfaces. The TOUGHREACT includes a module to describe effective porosity and permeability changes based on the modified cubic law, so the real-time change of the fracture permeability can be reflected during the flow simulation. Considering the coupled thermal-hydraulic-mechanicalchemical processes of discontinuity, it becomes evident that the chemical processes under repository conditions (long-term, high temperature, and high pressure) can disturb the hydraulic performance of the natural barrier, so further research is required to characterize the chemically-induced coupled processes for assessing the long-term performance of the natural barrier system.

• Saeha Kwon(Korea Atomic Energy Research Institute (KAERI)) Corresponding author
• Changsoo Lee(Korea Atomic Energy Research Institute (KAERI))
• Jin-Seop Kim(Korea Atomic Energy Research Institute (KAERI))