This study presents distribution of naturally occurring radioactive materials in groundwater in Jeju island. Radon (222Rn) and potassium (40K) concentrations were performed by using Liquid Scintillation Counter and Ion Chromatograph respectively. In addition, the activities of uranium and thorium nuclides were analyzed by Inductively Coupled Plasma Mass Spectroscopy. Groundwater samples were collected from 9 sites of water intake facilities for wide area supply in Jeju island from September 2022 to September 2023. The 40K concentrations of groundwater ranged between 0.050 and 0.400 Bq·L-1. The radon concentrations in groundwater were in the range of 0 to 60 Bq L-1, and there was no groundwater exceeding the range of 148 Bq L-1 proposed by the US EPA. The distribution of uranium and thorium in groundwater varied from 0 to 500 ng L-1 and 0 to 2.4 ng L-1, respectively. The concentrations of uranium did not exceed 30 μg L-1, thresholds indicated by the US EPA. By analyzing the concentrations of 40K, 222Rn, 238U and 232Th, the annual effective dose of residents can be assessed. The evaluated residents’ effective dose from natural radionuclides due to intake of drinking water is less than the recommended value of 100 μSv y-1. Consequently, this study indicates that the cancer risks of the residents in Jeju island from naturally occurring radioactive materials ingested with water is insignificant.