This study evaluated the emission characteristics of volatile organic compounds (VOCs) from 29 asphalt concrete (ascon) manufacturing facilities in South Korea. VOC concentrations were measured inside industrial stacks and storage silos and during and after the truck loading process. Based on these measurements, emission factors were calculated according to facility type and fuel consumption rate. Afterward, they were compared with emission factors set by the United States Environmental Protection Agency (U.S. EPA). The major VOCs emitted from ascon manufacturing facilities were identified as benzene, toluene, ethylbenzene, and the xylene isomers (o-xylene, m-xylene, and p-xylene). The emission concentrations of the VOCs were found to be relatively higher inside industrial stacks and storage silos. Emission factors varied depending on the facility type, with lower values observed in manufacturing facilities using recycled ascon compared to conventional ascon facilities. The emission factors derived in this research were found to be lower than those reported by the U.S. EPA. This difference is attributed to the fact that the emission factors in this study were calculated based on VOC concentrations after treatment by pollution control facilities. As the Clean Air Policy Support System (CAPSS) also sets emission factors based on post-treatment concentrations, this study’s findings can serve as fundamental data to enhance the accuracy of VOC emission estimations.