The air dilution olfactory method to measure complex odors needs to store and carry odor samples from the field sampling until the analysis in laboratories. Until the analysis of sample in the laboratory, odor dilution factor (odor sensitivity) in the sample bag may decrease over time depending on the characteristics of each odor substances. This is one of the limitation for the air dilution olfactory method. Thus, the air dilution device enable to measure without loss in complex odors of samples. Recently, many studies on the performance test of on-site air dilution devices, i.e., field olfactometer, has been conducted to figure out the feasibility of the field olfactometers. In this study, seven odor samples were collected from five odor emission source sites. And comparative analysis with the air dilution olfactory method was carried out to assess the field applicability of the olfactometer. As results, the performance of the field olfactometer used in this study is regared as the affordable method. The dilution factors from between two methods showed the similar values, indicating low values of standard deviations. In order to ensure the accuracy and precision of measurement data using the field olfactometer, methodology minimized variables (that may affect measurement) needs to establish.

This study investigated the odor emission characteristics of fertilizer manufacturing facilities. The characteristics were evaluated by measuring the odor concentration at the outlet and site boundary of the complex fertilizer and organic fertilizer manufacturing facilities. The evaluation process utilized the air dilution sensory method and PTR-ToF-MS. The complex odor dilution factor ranged from 100 to 120 times at the outlet of the compound fertilizer manufacturing facility. Specifically, the concentrations of Ammonia and Aldehydes were relatively high as designated odor substances. For the organic fertilizer facility, the dilution factor for complex odors was measured up to a maximum of 3,000. And, designated odorants such as Ammonia and Hydrogen sulfide were measured at levels up to parts per million (ppm). The odor contribution assessment of the fertilizer manufacturing facilities showed that the complex fertilizer facility exhibited similar contributions from Aldehydes and Sulfur compounds. On the other hand, the organic fertilizer facility had the highest contribution of over 62% from Sulfur compounds. As odor substances are easily changed and diffused according to weather conditions, it is difficult to obtain representative data according to the measurement time. Therefore, if continuous monitoring of odorous substances is performed using equipment that can be measured in real time without pretreatment, it becomes feasible to identify odor emission sources and regional spatio-temporal distribution. This information would then serve as a basis for analyzing odorant contamination characteristics and establishing appropriate countermeasures.

Incheon is an area where complaints about odors occur frequently and there are many sources of odor emission. In this study, we used a real-time monitoring device to measure the odorous concentration near the areas where there are complaints about odors. The measurements were carried out for the three areas (G, C, S) that are located around emissions sources. G is situated in an industrial complex that has a reputation for being one of the most foul smelling regions of Incheon. A petroleum refining plant and storage facility are located around C. S is a residential area nearby an industrial site. The concentration of major designated odor substances in the G and S areas satisfied the site boundary emission standards. With regard to the characteristics of odor substances by region, although the C area region had the highest odor intensity among the three regions due to the odor intensity near the oil storage facility areas G and S were similar in terms of odor intensity. In the region of the G area, the odor intensity was slightly higher at the northern side of t he industrial complex. In terms of the odor intensity of the designated odor substances, trimethyl amine was the strongest, followed by hydrogen sulfide. The real time monitoring system was necessary to analyze the changing trends of odor substances and for the determination of major odor sources. This study was conducted to identify the material causes of odors in areas of Incheon where there are frequent complaints about major odors.

The annual number of odor complaints increased about 10 times over 14 years from 4,302 in 2005 to 40,854 in 2019, in Korea. Especially, livestock facilities account for more than 50% of the odor complaints and the swine farms account for the most odor complaints among livestock. It is therefore necessary to manage swine farms as the major odor emission source. In this study, a real-time odor monitoring system equipped with PTR-TOF-MS (proton transfer reaction time-of-flight mass spectrometric) was used to measure the odorous substances in two swine farms. Odorous substances emitted from outlets were sampled and measured at the two types of swine farms. In addition, the boundary spots were designated as measurement points. As a result, the rankings of the odorous substances in order, from highest to lowest, were ammonia, acetaldehyde, methyl mercaptan, fatty acids, etc. and the level of odor intensity was 0.8-4.4 at the outlet of the swine farms. The concentration at the boundary decreased between 1/100 ~ 1/10000 compared to the concentration emitted from outlets. Base on the results of evaluating odor activity values, Skatole and p-Cresol were estimated as major odor substances in swine farms.

In this study, actual odor conditions were investigated in restaurants, livestock facilities, and major odor discharge facilities around daily life, and an odor modeling program was performed to find ways to improve odors in odor discharge facilities. The odor modeling results of restaurants around daily life showed that the complex odor concentration of large restaurants, which are close to residential areas, is higher than the acceptable complex odor standard at the receiving point. It was judged that a plan to increase the height of the restaurant odor outlets and a plan to reduce the amount of odor discharge was necessary. As a result of modeling the life odor of livestock housing facilities, when the distance from the housing facility is far away, the actual emission concentration is much lower than the acceptable emission concentration at the receiving point. It was judged that such facilities need to be reviewed for ways to reduce the emission of odorous substances, such as sealing the livestock housing facilities or improving the livestock environment. The main odor emission business sites that show complex odor concentration as 1,000 times or greater than the outlet odor emission standard were businesses associated with surfactant preparation, compounded feed manufacturing, textile dyeing processing, and waste disposal. Due to the separation distance and high exhaust gas flow rate, it was found that odor reduction measures are necessary. In this study, it was possible to present the allowable odor emission concentration at the discharge facilities such as restaurants, livestock houses, and industrial emission facilities by performing the process of verifying the discharge concentration of the actual discharge facility and the result of living odor modeling. It is believed that suitable odor management and prevention facilities can be operated.

In this study, real-time monitoring of air quality using a real-time mobile monitoring system was conducted to identify the emission characteristics and current status of air pollutants and odorous substances that are mainly generated in domestic dyeing industrial areas and to trace the pollutant sources. The concentration of toluene in the industrial area was detected up to 926.4 ppb, which was 3 to 4 times higher than that of other industrial areas. The concentration of methylethylketone was 124.7 ppb and the concentration of dichloromethane was 129.5 ppb. Acrolein concentration was highest at E point at 521.6 ppb, methanol concentration was highest at D point at 208.8 ppb, and acetone concentration was highest at M and N points at 549.3 ppb. The most frequently detected concentration of pollutants in the air quality monitoring results in the industrial area was, in descending order, toluene > methanol > acrolein > dichloromethane > acetone, which was similar to the chemical emissions used in the industrial area by the Pollutant Release and Transfer Register data. The concentration of odorous substances measured in real time was compared with the concentration of minimum detection, and the concentration of hydrogen sulfide was about 10 times higher than the concentration of minimum detection at A point, which was judged to be the main odorous cause of A point. In the future, if the real-time mobile measurement system is constructed to automatically connect wind direction/wind speed, PRTR (Pollutant Release and Transfer Register) data and SEMS (Stack Emission Management System) data, etc., it was judged that more accurate monitoring could be performed.

In this study, the grid field olfactory odor method was supplemented to the domestic situation in the surrounding areas of a domestic science industrial complex. The actual condition of the occurrence of odor frequency in the field was then investigated over the first period of late spring to summer and the second period of autumn in 2017. The frequency of odor occurrence in the area around the science industrial complex was increased as odor discharge facilities in the nearby area were concentrated. The odor occurrence frequency of the total period was 0.09~0.28, that of the first period was 0.08~0.32, and that of the second period was 0.05~0.25. The odor occurrence frequency in summer was higher than in autumn. The frequency by which the measurement of odor occurrence by smell type was most dominant was mainly smell of chemicals, plastics, and livestock houses during the first period, and the smell of chemicals, burning gases, and plastics during the second period. And the frequency of each smell type was judged to be different according to season. The odor occurrence frequency was measured as higher than 0.15, which is the standard of Germany's odor frequency in an industrial area, and it was judged that measures for odor management in the region were necessary. Since most of the odor discharge facilities are non-continuous systems and the odor generation frequency is more important than the concentration of the minimum detection concentration, it was judged that the German grid method can reflect the odor occurrence characteristics of the odor complaints or receptors for a certain period of time compared to the domestic measurement method. In the future, it was judged that the field olfactory odor method would be able to replace the evaluation method of odor assessment in Korea with the survey method of odor assessment under actual conditions in areas where it is difficult to access the odor discharge source or the receptor where odor complaints occur.

In this study, we conducted a survey on odor characteristics of single odor and collective odor facilities using the German olfactory odor method and carried out the odor frequency modeling. The influence of the odor from a sewage treatment plant, which is a single discharge facility, was strong in the eastern and northern parts of the plant and appeared to be in good agreement with the areas where the odor complaints were frequent. The German olfactory method reflects the odor complaints and odor occurrence characteristics of the receptors as compared with the domestic odor measurement method. The influence of the odor from the odor control area, which is a collecting and discharging facility, showed a tendency in which the sum of the odor occurrence frequency increased with the proximity of the odor discharge facility to the dense industrial complex. Furthermore, it was judged that it is not easy to extract the odor frequency results for individual facilities because the survey subject is the group discharge facility area. Therefore, it will be necessary to introduce a method to manage odor in the future. In this study, the measurement of odor frequency using the German olfactory odor method is partially applied to some odor sources. Appropriately, it is not applicable to various emission sources. However, the odor measurement method based on odor occurrence frequency and odor sensory can be used for investigation of the actual condition, permits of odor discharge facilities and the environmental review.

The purpose of this study was to investigate the current status of odor and to examine the application method of the odor emission standard in a restaurant environment. The complex odor dilution concentrations (“times”) and odor compounds were measured in 8 restaurants. The highest complex odor dilution times were 966 in outlets and 97 in site boundaries of C restaurants. The average complex odor dilution times were 632 in outlets and 29 in site boundaries, which exceeded the allowable odor discharge standard of residential areas. Eighteen of the 22 specified offensive odor substances were detected. Aldehyde-type substances showed high concentrations, and the highest concentration of ethanol was detected in addition to the designated odorous substances. Dichloromethane, benzene, and phenol, which are harmful air pollutants, were also detected. The odorant concentrations of restaurants were found to exceed the odor standard threshold in A, B, and F restaurants. Upon review of the Japanese-style odor index respective to restaurant odor, it is difficult to apply an equivalent emission allowance standard as the permissible emission standard of the workplace. It is necessary to regulate emission standards by different emission standards. In the future, it will be necessary to determine how to measure the odor index and how to apply the odor emission standard to everyday facilities, such as restaurants, grocery stores, etc.

The study analyzed performance assessment factors of VOCs odor sensors from 3 different manufacturers, such as minimum detection limit, humidity stability and temperature stability. Through the minimum detection limit assessment, it was found that a VOCs sensor was able to detect TVOCs at the concentration of 5 ppb. The standard deviation ratio was over 10%, and it increased as humidity rose. The range of temperatures in which the VOCs odor sensor using photoionization could operate was between 25oC and 40oC, and the sensor output values were unstable at low temperatures. In terms of the temperature stability of the metal oxide semiconductor sensor for measuring complex odors, the sensor output values dropped considerably to 0~10oC, and were similar to the concentrations of odorous gases generated at 25oC. The results of the test of VOCs odor sensor outputs after temperature and humidity pre-treatment revealed that the respective stable output values at 50% humidity and 25oC were similar to the concentrations of manufactured odors. In terms of temperature and humidity stability of the VOCs odor sensors, all target VOCs substances had stable output values at 25oC to 40oC and at 50% to 65% relative humidities, and unstable values at low temperatures and high humidities. Therefore, the implementation of pre-treatment systems including temperature and humidity correction (25~40oC, 50~65% RH) is required for the stable use of VOCs odor sensors.

The study analyzed performance assessment factors of odor sensors from 4 different manufacturers, including minimum detection limit, humidity stability and temperature stability. In the minimum detection limit assessment, only one electrochemical gas sensor was able to detect ammonia and hydrogen sulfide at the concentration of 5 ppb. The standard deviation ratio was over 10%, and it increased as humidity rose. The range of temperatures in which the electrochemical and photoionization gas sensors could function well was between 25oC and 40oC, and the sensor output values were unstable at low temperatures. Regarding the temperature stability of the metal oxide semiconductor sensor for measuring complex odors, the sensor output values dropped considerably to 0~10oC, and were similar to the concentrations of odor gases generated at 25oC. The results of the test of odor sensor outputs after temperature and humidity pre-treatment revealed that the respective stable output values at 50% humidity and 25oC were similar to the concentrations of manufactured odors. In terms of temperature and humidity stability of the NH3, H2S and Complex odor sensors, all target substances had stable output values at 25~40oC and 50~65% relative humidity, and unstable values at low temperatures and high humidity. Therefore, implementing pretreatment systems including temperature and humidity correction (25~40oC, 50~65% RH) is necessary for the stable use of odor sensors.

In this study, odor sensors were evaluated in two areas, which were reproducibility of measurements and linearity and correlation of results. The evaluation of linearity and correlation showed that the linearity of the measurement object substance at low, medium and high concentrations of all intervals, and correlation (R2) also appeared to be quite high, at 0.8 to 0.9. Specific performance evaluation results of ammonia, hydrogen sulfide, TVOC and complex odor sensor to the individual substances are somewhat different, but the result have able tendencies. All odor sensors showed detectable in all metrics at 5 ppb concentration in temperature 25oC, humidity 50%. However, there is needs to be determined that in many cases the standard deviation is 10% or more in 5 ppb, and reproducibility appears in the high concentration region with a standard deviation of less than 10%. Because complex odor sensor (MOS sensor) output value is relatively accurate concentration value for the odor and the reaction was stable, MOS sensor is to be considered methods for measuring the complex odor. Reactivity of ammonia, hydrogen sulfide and TVOC odor sensor to the concentration of individual odor substances stably displayed, but the reactivity of the mixture material showed the same trend, however, the hydrogen sulfide and TVOC sensor reactivity were unstable. There is thus a need to maintain the proper temperature and humidity environmental operating condition of odor sensors.

In this study, a correlation analysis of odor was performed in order to assess the reliability and the field applicability of the Odorous gas sensor for continuous real-time monitoring. Hydrogen sulfide was found to have a correlation of 41.5~65.8%, and Ammonia is was found to have very low correlation in less than 200 ppb concentration. Reactivity evaluation result, hydrogen sulfide is the reactivity was higher than the low concentration condition of 100 ppb or less indicated by 31.3~36.4% in the 100 ppb or more high density condition based on the reference density value. For ammonia was very low reactivity in the low-concentration conditions below 200 ppb. TVOC and composite odor assessment did not occur Reactivity no reference concentration value, the specific comparison between both sensors showed a similar trend. In the same Odorous gas sensor accuracy between the result, 40.3~130.6% hydrogen sulfide, ammonia, 69.1~104.9%, TVOCs is 24.7~98.6%, exhibited human odor intensity from 5.5~33.2%.

This research determined the threshold value of 10 specified offensive odor substances based on the 3 point comparison sensory method. The panelist's thresholds were calculated by taking the arithmetic, geometric mean, and 50th percentile. Three methods of calculating the odor thresholds from the same data are compared. For 10 odor substances, the panelist's thresholds revealed a logarithmically normal distribution. The 50th percentile was the best method among the three methods of calculating the odor threshold from the 270 thresholds of 18 panels. As a result, the threshold values of individual odor substances, including i-valeric acid, n-valeric acid, n-butyric acid, and butyl acetate ranged between 0.0001~0.006 ppm, while the values of methyl ethyl ketone and toluene were relatively higher than that of other substances at 0.7107 ppm and 1.2139 ppm, respectively. The threshold values of the 10 specified odor substances were compared in Korea and overseas, which showed that the characteristics of sensory response varied by substance and nation.

In this study we investigated odor (hydrogen sulfide) dispersion around a cubic building by using commercial FLUENT CFD code. The FLUENT Shear-Stress Transport (hereafter SST) k-ω turbulence model was used to simulate odor dispersion from an odor source. The results were compared with a wind tunnel experiment and other simulation results. SST k-ω turbulence model provided good grounds for making reasonable predictions about the building surface concentrations and concentration profiles of selected leeward positions of the cubic building. It was found that a vent, which was positioned 7 m above the top of the square building center, decreased the plume length lower by 0.73 and increased the plume height by 1.43 compared to roof top vents. It was also found that by increasing the vent height there a corresponding decrease in the maximum dimensionless concentration around the roof surface.