In this study, the performances of H2S, NH3, and HCl sensors for real-time monitoring in small emission facilities (4, 5 grades in Korea) were evaluated at high concentration conditions of those gases. And the proper approach for the collection of reliable measurement data by sensors was suggested through finding out the effect on sensor performances according to changes in temperature and humidity (relative humidity, RH) settings. In addition, an assessment on sensor data correction considering the effects produced by environmental settings was conducted. The effects were tested in four different conditions of temperature and humidity. The sensor performances (reproducibility, precision, lower detection limit (LDL), and linearity) were good for all three sensors. The intercept (ADC0) values for all three sensors were good for the changes of temperature and humidity conditions. The variation in the slope value of the NH3 sensor showed the highest value, and this was followed by the HCl, H2S sensors. The results of this study can be helpful for data collection by enabling the more reliable and precise measurements of concentrations measured by sensors.

The air dilution olfactory method to measure complex odors needs to store and carry odor samples from the field sampling until the analysis in laboratories. Until the analysis of sample in the laboratory, odor dilution factor (odor sensitivity) in the sample bag may decrease over time depending on the characteristics of each odor substances. This is one of the limitation for the air dilution olfactory method. Thus, the air dilution device enable to measure without loss in complex odors of samples. Recently, many studies on the performance test of on-site air dilution devices, i.e., field olfactometer, has been conducted to figure out the feasibility of the field olfactometers. In this study, seven odor samples were collected from five odor emission source sites. And comparative analysis with the air dilution olfactory method was carried out to assess the field applicability of the olfactometer. As results, the performance of the field olfactometer used in this study is regared as the affordable method. The dilution factors from between two methods showed the similar values, indicating low values of standard deviations. In order to ensure the accuracy and precision of measurement data using the field olfactometer, methodology minimized variables (that may affect measurement) needs to establish.

We used the measurement data derived from a proton transfer reaction time-offlight mass spectrometry (PTR-ToF-MS) to ascertain the source profile of volatile organic compounds (VOCs) from 4 major industrial classifications which showed the highest emissions from a total of 26 industrial classifications of A industrial complex. Methanol (MOH) was indicated as the highest VOC in the industrial classification of fabricated metal manufacture, and it was followed by dichloromethane (DM), ethanol (EN) and acetaldehyde (AAE). In the industrial classification of printing and recording media, the emission of ethylacetate (EA) and toluene (TOL) were the highest, and were followed by acetone (ACT), ethanol (EN) and acetic acid (AA). TOL, MOH, 2-butanol (MEK) and AAE were measured at high concentrations in the classification of rubber and plastic manufacture. In the classification of sewage, wastewater and manure treatment, TOL was the highest, and it was followed by MOH, H2S, and ethylbenzene (EBZ). In future studies, the source profiles for various industrial classifications which can provide scientific evidence must be completed, and then specified mitigation plans of VOCs for each industrial classification should be established.

Recently, there has been growing interest in harmful substances released from household items such as volatile organic compounds (VOCs) and this has increased people’s environmental awareness. In this study, adhesives and manicures were used as samples of indoor household goods and formaldehyde emission and tested over time under temperature conditions of 15oC, 25oC, 35oC, and 45oC. The small chamber method as the indoor air quality process test method was employed and used to evaluate the concentration of formaldehyde emissions. As a result, formaldehyde emissions gradually decreased over time in both tests using adhesives and manicures. The cumulative emission showed a logarithmic function over time, and the formaldehyde can be released for longer periods of time at lower temperature conditions. The logarithmic value and response time showed linear relationships, and it can be inferred that the formaldehyde was released from the sample through the first order reaction. Furthermore, the relationship between temperature and velocity constants which was determined using the Arenius linear equation showed that the reaction rate of formaldehyde can be estimated by a temperature change.

Environmental fundamental facilities have different odor emission characteristics depending on the type of treatment facilities. To overcome the limitations of the olfactometry method, research needs to be conducted on how to calculate the dilution factor from the individual odor concentrations. The aim of this study was to determine the air dilution factor estimated from manually measured concentration data of individual odor substances (22 specified odor species) in three environmental treatment facilities. In order to calculate the optimum algorism for each environmental fundamental facility, three types of facilities were selected, the concentration of odor substances in the exhaust gas was measured, and the contribution of the overall dilution factor was evaluated. To estimate the dilution factor, four to six algorism were induced and evaluated by correlation analysis between substance concentration and complex odor data. Dilution factors from O municipal water treatment (MWT) and Y livestock wastewater treatment (LWT) facilities showed high level of dilution factors, because concentration levels of hydrogen sulfide and methylmercaptan, which had low odor threshold concentrations, were high. In S food waste treatment (FWT) facility, the aldehyde group strongly influenced dilution the factor (dominant substance: acetaldehyde, i-valeraldhyde and methylmercaptan). In the evaluation of four to six algorism to estimate the dilution factor, the vector algorism (described in the text) was optimum for O MWT and Y LWT, while the algorism using the sum of the top-three dominant substances showed the best outcome for S FWT. In further studies, estimation of the dilution factor from simultaneously monitored data by odor sensors will be developed and integrated with the results in this study.

The objectives of this study were (i) to evaluate the effects of temperature and relative humidity on two electrochemical sensors measuring hydrogen sulfide and ammonia using a laboratory testing system for various sensors, and (ii) to propose a calibration method for those concentrations to collect more reliable monitoring data. The effect of temperature and relative humidity was tested under three different conditions, respectively. The linearities measured data under all different conditions for the relative humidity and temperature were excellent, indicating more than 0.99 of R2 for both odor sensors. Under the condition of zero concentration, baselines (intercepts) at zero increased with increasing relative humidity for both hydrogen sulfide and ammonia sensors. The rate of gas concentration according to ADC variation (slopes) increased with increasing relative humidity about only the hydrogen sulfide sensor. In this study, slope, and intercept are utilized for calibration of hydrogen sulfide and ammonia concentration, and the reliability of the data of hydrogen sulfide and ammonia sensors is further enhanced by the relational expression obtained by this paper.

흑연 동위원소 비율법(GIRM)은 비핵화 검증 도구로써 흑연감속로의 플루토늄 생산량을 예측하는데 사용된다. 원자로가 가동되면 238U의 중성자 포획 반응에 의해 플루토늄이 생성되어 축적되고 동시에 흑연 내 불순물도 핵반응을 통해 다른 핵종 으로 바뀌기 때문에 플루토늄의 생성량과 불순물의 농도는 일정한 상관 관계를 갖는다. 이러한 상관관계에도 불구하고 어느 특정 시점에서의 불순물의 농도는 불순물의 초기 농도에 의존하기 때문에 불순물의 초기 농도가 알려지지 않으면 불순물의 절대 농도만으로 플루토늄 생산량을 예측하는 것은 불가능하다. 그러나 불순물의 초기 동위원소 비율은 초기 불순물 농 도에 상관없이 알려져 있기 때문에 불순물의 동위원소 비율과 플루토늄 생산량의 관계는 흑연감속로에서 플루토늄 생성량을 예측하는 유용한 도구가 될 수 있다. 흑연동위원소 비율법의 지표 원소로 Boron, Lithium, Chlorine, Titanium, Uranium 등이 이용되는 것으로 알려져 있다. 위 지표원소의 동위원소 비와 플루토늄 생성량 사이의 상관 관계가 초기 불순물 농도에 의존하지 않는지를 네 가지 다른 흑연 불순물 조성을 이용하여 평가하였다. 10B/11B, 36Cl/35Cl, 48Ti/49Ti, 235U/238U은 흑연의 초기 불순물 농도에 상관없이 누적 플루토늄 생성량과 일관된 상관 관계를 갖는다. 이러한 원소들은 다른 원소의 핵반응에 의해 해당 원소의 동위원소가 생성되지 않기 때문이다. 반면 6Li/7Li과 플루토늄 생성량의 상관관계는 흑연 내 불순물의 초기 농도에 의존한다. 7Li은 6Li의 중성자 포획 반응에 의해서 생성되기도 하지만 10B의 (n, α)반응으로도 생성되는 것이 더 지배 적이기 때문에 10B의 초기 농도가 7Li의 생성량에 영향을 미치는 것이다. 따라서 Lithium은 흑연 동위원소 비율법을 위한 지표 원소로 적절하지 않음을 알 수 있다.

We used three gas sensors to monitor hydrogen sulfide, ammonia, and volatile organic compounds (VOCs), which were frequently emitted from environmental facilities, such as municipal wastewater treatment, livestock manure treatment, and food waste composting facilities. Two electrochemical (EC) sensors for detecting hydrogen sulfide and ammonia, and a photoionization detector (PID) sensor for detecting VOCs were characterized in this study. The performance of their linearity by concentration levels, lower detection limit (LDL), repeatability, reproducibility, precision, and response time were tested under the laboratory condition. The linearity according to concentration levels were favorable for all three sensors with high correlation coefficients (R2 > 0.98). The ammonia sensor showed the highest LDL (18.6 ppb) and the hydrogen sulfide and VOC sensors showed 22.3 ppb and 26.7 ppb of LDL, respectively. The reproducibility and precision were favorable for all three sensors, indicating a lower relative standard deviation (RSD) than 0.9% in the reproducibility test and 7.2% in the precision test. The response times to reach target concentration were varied from 1 to 12 minutes. The ammonia sensor needed 12 minutes of response time at 1 ppm target the NH3 concentration and the hydrogen sulfide and VOC sensors needed less than 2 minutes of response time.

In this study, we conducted a survey on odor characteristics of single odor and collective odor facilities using the German olfactory odor method and carried out the odor frequency modeling. The influence of the odor from a sewage treatment plant, which is a single discharge facility, was strong in the eastern and northern parts of the plant and appeared to be in good agreement with the areas where the odor complaints were frequent. The German olfactory method reflects the odor complaints and odor occurrence characteristics of the receptors as compared with the domestic odor measurement method. The influence of the odor from the odor control area, which is a collecting and discharging facility, showed a tendency in which the sum of the odor occurrence frequency increased with the proximity of the odor discharge facility to the dense industrial complex. Furthermore, it was judged that it is not easy to extract the odor frequency results for individual facilities because the survey subject is the group discharge facility area. Therefore, it will be necessary to introduce a method to manage odor in the future. In this study, the measurement of odor frequency using the German olfactory odor method is partially applied to some odor sources. Appropriately, it is not applicable to various emission sources. However, the odor measurement method based on odor occurrence frequency and odor sensory can be used for investigation of the actual condition, permits of odor discharge facilities and the environmental review.

본 연구에서는 현행 악취공정시험방법에 나타나있는 공기희석 관능법을 사용하여 물질농도와 희석배수와의 관계를 살펴보기 위해 프로피온산, 뷰틸산, 발레르산, i-발레르산 및 i-뷰틸알코올에 대한 물질농도와 희석배수를 측정하였다. 또한 상관관계식을 이용하여 지정악취물질의 농도 규제치의 적정성을 검토하였다. 1. 판정인에 의해 측정된 대상물질의 물질농도와 희석배수의 상관관계는 식 Log C = Af·Log D + 0.5에 의해 적절하게 나타났으며, 총 22종의 지정 악취물질별 상관관계식의 기울기 값의 범위는 0.9023~1.2012으로 이소발레르알데하이드가 가장 작고, 뷰틸알데하이드가 가장 큰 것으로 나타났다. 2. 물질별 관계식으로부터 산출된 희석배수 15와 20에 해당되는 물질농도와 최소감지농도와의 비를 구한 결과, 각 물질의 농도비가 희석배수 15 및 20과 유사한 수치를 나타내 물질별 관계식이 의미가 있는 것으로 추정되었다. 3. 물질별 관계식으로부터 산출된 희석배수 15와 20에 해당되는 물질농도와 현행 물질농도 기준치와 의 비교를 통하여 기준치의 적정 수준 여부를 검토 해본 결과, 프로피온산과 뷰틸산의 경우는 기준치가 상대적으로 낮게 설정된 것으로 판단되며, 발레르산, 이소발레르산과 뷰틸알코올의 경우 물질농도 기준치가 적정 수준인 것으로 추정된다. 본 연구결과는 현행 악취방지법의 부지경계선에서 복합악취 농도 규제기준에 대한 개선방안 및 지정악취 물질들의 물질농도와 악취강도, 희석배수간의 상관관계 및 특성연구 등의 기반 자료로 사용될 수 있을 것이다.

In this study, swine and cattle farms located in Jeollanam-do were selected to analyze and evaluate the components of odorants in livestock facilities. In addition, a preliminary survey of the literature was conducted to establish a sampling and analysis method for phenol and indoles which are major components of odor emissions from livestock facilities, yet are not regulated by the laws. To establish a sampling and analysis method for phenol and indoles, Tedlar bag and Tenax-TA sorbent tube was used as background concentration of blank sample and samples according to the elapsed time. The results obtained indicate the GC/MS analysis with Tenax-TA sorbent tube sampling was an effective method for measuring the compounds of phenol and indoles. In the swine facility, the rankings of the odorants in order, from highest to lowest, were ammonia, sulfuric compounds, phenol/indoles, volatile fatty acids. The main odorants were hydrogen sulfide (41.3%) and 4-methylphenol (p-cresol, 13.9%). In the swine slurry storage, hydrogen sulfide (33.7%), ammonia (18.8%), and 3-methylindole (skatole, 15.7%) were the main odorants, and hydrogen sulfide (31%) and i-valeric acid (32.4%) were the main odorants in the cattle farms.

The study analyzed performance assessment factors of VOCs odor sensors from 3 different manufacturers, such as minimum detection limit, humidity stability and temperature stability. Through the minimum detection limit assessment, it was found that a VOCs sensor was able to detect TVOCs at the concentration of 5 ppb. The standard deviation ratio was over 10%, and it increased as humidity rose. The range of temperatures in which the VOCs odor sensor using photoionization could operate was between 25oC and 40oC, and the sensor output values were unstable at low temperatures. In terms of the temperature stability of the metal oxide semiconductor sensor for measuring complex odors, the sensor output values dropped considerably to 0~10oC, and were similar to the concentrations of odorous gases generated at 25oC. The results of the test of VOCs odor sensor outputs after temperature and humidity pre-treatment revealed that the respective stable output values at 50% humidity and 25oC were similar to the concentrations of manufactured odors. In terms of temperature and humidity stability of the VOCs odor sensors, all target VOCs substances had stable output values at 25oC to 40oC and at 50% to 65% relative humidities, and unstable values at low temperatures and high humidities. Therefore, the implementation of pre-treatment systems including temperature and humidity correction (25~40oC, 50~65% RH) is required for the stable use of VOCs odor sensors.

This study aims to understand the correlation between odor intensity and dilution factor using the Air Dilution Olfactory Method, which is suggested in the Standard Method of Odor Compounds, by measuring odor intensity and dilution factor for fatty acids and i-butyl alcohol. For the measurement, 18 panel members were selected through a panel test, and odor intensity and dilution factor by substance produced from the selected panel were estimated. The estimation showed that the correlation of odor intensity with dilution factor for a fatty acids and i-butyl alcohol can be reasonably expressed by the equation I = A·log D + 0.5 (I : odor Intensity, D : dilution factor, A : material constant). The material constant was in order of propionic acid 2.0709, n-butyric acid 1.6006, n-valeric acid 1.3369, i-valeric acid 1.182, i-butyl alcohol 1.4326. The geometric average of increased dilution factor for the 5 compounds is about 4.8 time, 3.0 time for propionic acid and 7.0 tme for i-valeric acid due to odor intensity 1 increasing. It is suggested that the result of this study could be used as a base data for research on measures to improve the regulation standards for complex odor concentrations at a boundary sites in operation.

The study analyzed performance assessment factors of odor sensors from 4 different manufacturers, including minimum detection limit, humidity stability and temperature stability. In the minimum detection limit assessment, only one electrochemical gas sensor was able to detect ammonia and hydrogen sulfide at the concentration of 5 ppb. The standard deviation ratio was over 10%, and it increased as humidity rose. The range of temperatures in which the electrochemical and photoionization gas sensors could function well was between 25oC and 40oC, and the sensor output values were unstable at low temperatures. Regarding the temperature stability of the metal oxide semiconductor sensor for measuring complex odors, the sensor output values dropped considerably to 0~10oC, and were similar to the concentrations of odor gases generated at 25oC. The results of the test of odor sensor outputs after temperature and humidity pre-treatment revealed that the respective stable output values at 50% humidity and 25oC were similar to the concentrations of manufactured odors. In terms of temperature and humidity stability of the NH3, H2S and Complex odor sensors, all target substances had stable output values at 25~40oC and 50~65% relative humidity, and unstable values at low temperatures and high humidity. Therefore, implementing pretreatment systems including temperature and humidity correction (25~40oC, 50~65% RH) is necessary for the stable use of odor sensors.

This study aims to evaluate the relationship between concentration and odor intensity using the odor sensory method for 4 types of fatty acid compounds and i-butyl alcohol. For the measurement, 18 panelists were selected based on several criteria through a panel test. Panelists chosen for their closely similar sensitivities provided more reproducible values. The estimation showed that the correlation of the concentration with odor intensity for the 5 compounds, including the fatty acid compounds and i-butyl alcohol can be reasonably expressed by the Weber-Fechner equation. Notably the standards regulation fatty acid concentrations are very strict, and the butyl acetate standards are very loose. It is suggested than the results of this study can be used as basic data for research on measures to improve the regulation standards on complex odor concentrations on site boundaries in operation, as well as the correlation between concentration and odor intensity for the designated foul odor substances, and their characteristics.

In this study, odor sensors were evaluated in two areas, which were reproducibility of measurements and linearity and correlation of results. The evaluation of linearity and correlation showed that the linearity of the measurement object substance at low, medium and high concentrations of all intervals, and correlation (R2) also appeared to be quite high, at 0.8 to 0.9. Specific performance evaluation results of ammonia, hydrogen sulfide, TVOC and complex odor sensor to the individual substances are somewhat different, but the result have able tendencies. All odor sensors showed detectable in all metrics at 5 ppb concentration in temperature 25oC, humidity 50%. However, there is needs to be determined that in many cases the standard deviation is 10% or more in 5 ppb, and reproducibility appears in the high concentration region with a standard deviation of less than 10%. Because complex odor sensor (MOS sensor) output value is relatively accurate concentration value for the odor and the reaction was stable, MOS sensor is to be considered methods for measuring the complex odor. Reactivity of ammonia, hydrogen sulfide and TVOC odor sensor to the concentration of individual odor substances stably displayed, but the reactivity of the mixture material showed the same trend, however, the hydrogen sulfide and TVOC sensor reactivity were unstable. There is thus a need to maintain the proper temperature and humidity environmental operating condition of odor sensors.

In this study, a correlation analysis of odor was performed in order to assess the reliability and the field applicability of the Odorous gas sensor for continuous real-time monitoring. Hydrogen sulfide was found to have a correlation of 41.5~65.8%, and Ammonia is was found to have very low correlation in less than 200 ppb concentration. Reactivity evaluation result, hydrogen sulfide is the reactivity was higher than the low concentration condition of 100 ppb or less indicated by 31.3~36.4% in the 100 ppb or more high density condition based on the reference density value. For ammonia was very low reactivity in the low-concentration conditions below 200 ppb. TVOC and composite odor assessment did not occur Reactivity no reference concentration value, the specific comparison between both sensors showed a similar trend. In the same Odorous gas sensor accuracy between the result, 40.3~130.6% hydrogen sulfide, ammonia, 69.1~104.9%, TVOCs is 24.7~98.6%, exhibited human odor intensity from 5.5~33.2%.

This research determined the threshold value of 10 specified offensive odor substances based on the 3 point comparison sensory method. The panelist's thresholds were calculated by taking the arithmetic, geometric mean, and 50th percentile. Three methods of calculating the odor thresholds from the same data are compared. For 10 odor substances, the panelist's thresholds revealed a logarithmically normal distribution. The 50th percentile was the best method among the three methods of calculating the odor threshold from the 270 thresholds of 18 panels. As a result, the threshold values of individual odor substances, including i-valeric acid, n-valeric acid, n-butyric acid, and butyl acetate ranged between 0.0001~0.006 ppm, while the values of methyl ethyl ketone and toluene were relatively higher than that of other substances at 0.7107 ppm and 1.2139 ppm, respectively. The threshold values of the 10 specified odor substances were compared in Korea and overseas, which showed that the characteristics of sensory response varied by substance and nation.

In this study we investigated odor (hydrogen sulfide) dispersion around a cubic building by using commercial FLUENT CFD code. The FLUENT Shear-Stress Transport (hereafter SST) k-ω turbulence model was used to simulate odor dispersion from an odor source. The results were compared with a wind tunnel experiment and other simulation results. SST k-ω turbulence model provided good grounds for making reasonable predictions about the building surface concentrations and concentration profiles of selected leeward positions of the cubic building. It was found that a vent, which was positioned 7 m above the top of the square building center, decreased the plume length lower by 0.73 and increased the plume height by 1.43 compared to roof top vents. It was also found that by increasing the vent height there a corresponding decrease in the maximum dimensionless concentration around the roof surface.

2011년에 전국 79개 악취검사기관을 대상으로 공기희석관능법에 대한 숙련도 시험을 실시하였다. 악취방지법의 부지 경계선과 악취 배출원의 배출허용기준을 모사한 2개의 합성복합악취를 숙련도 시험물질(proficiency testing materials, PTM)로 사용 하였다. 부지 경계선 시료는 7ppm의 톨루엔과 7ppm m-자일렌의 복합악취로 구성하였으며, 배출구 시 료는 10ppm DMS (dimethyl sulfide)와 10ppm DMDS (dimethyl disulfide)의 복합악취로 구성하였다. 숙련도 시험 결과는 기준값으로 평균과 중간값을 사용하고, 목표표준편차로 일반 표준편차, 로버스트 표준편차 및 변동계수를 사용하여 Z-점수를 평가하였다. 시험결 과의 변동계수는 PTMs의 냄새강도가 증가함에 따라 감소하였다. 복합악취에 대한 숙련 도 시험 결과는 악취희석배율보다 로그 스케일의 악취지수를 사용하여 평가하는 것이 적 절했다. 두 PTMs에 대한 참여기관의 Z-점수를 변동계수, 표준편차, 그리고 로버스트 표 준편차를 사용하여 평가할 때, 참여기관의 95%가 숙련도 기준을 만족하였다. 목표 표준 편차를 변동계수의 20%로 설정하였을 때 참여기관의 만족도 비율은 부지경계와 출구 PTM 시료에 대해 각각 90%와 95%로 양호하였다. 이러한 결과들로부터 부지경계와 출 구의 복합악취를 모사한 두 합성 PTMs 모두 복합악취의 숙련도 시험물질로 적합하였다.