Transition-metal phosphides (TMPs), a promising anode material for lithium-ion batteries (LIBs), are limited in application because of its serious volume effect in the cycle. In this work, a simple electrospinning strategy was proposed to restrict the grain size of CoP nanocrystals by nano-confined effect of carbon nanofibers with ligands. The addition of ligands not only could realize the uniform dispersion of CoP nanocrystals, but also strengthen the bond between the metals and carbon nanofibers. As a result, the CoP/CNF composite exhibits excellent lithium storage performance, and its reversible specific capacity could reach 1016.4 mAh g− 1 after 200 cycles at a current density of 200 mA g− 1. The research is anticipated to provide a new idea for the preparation of anode materials for lithium ion batteries.

Hydrogen energy is a promising source of renewable and clean energy for various industries, such as chemical, automobile, and energy industries. Electrolysis of water is one of the basic methods for the production of hydrogen energy. However, the high overpotential of the oxygen evolution reaction (OER) in water electrolysis has hindered the effective production of hydrogen using this method. Thus, the development of high-efficiency non-precious metal-based electrocatalysts for OER is extremely significant. In this study, we adopted a one-step hydrothermal method to fabricate Ni-based catalysts with N/Sdual doped graphene oxide/carbon nanotube (GO/CNT) supports using thiourea ( CH4N2S) and urea as the S source and the N source. It was observed that the amount of thiourea utilized in the synthesis of the catalyst affected the morphology, composition, and the electrochemical properties of the catalyst. For a GO/CNT-to-thiourea mass ratio of 1:10, the catalyst exhibited the highest activity, where the OER overpotential was 320 mV at a current density of 10 mA/cm2. This was attributed to the high specific surface area, high conductivity, and fast electron transport channels of the N/S-dual doped GO/ CNT composite. Furthermore, sulfurization of the Ni particles to form nickel sulfide played a significant role in enhancing the catalytic performance.

Understanding molting process in subterranean termites is a critical step to implement successful control program as chitin synthesis inhibitor baits interfere molting process of termites. In the present study, we report detailed molting process in Reticulitermes speratus kyushuensis Morimoto, 1968 that foraging workers start fasting period 5 days after they were collected and finished their entire molting process for the next 5 to 6 days. Ecdysis took less than an hour, specifically 9.2 ± 4.9 minutes from jack-knife posture to separation of the antenna and 36.6 ± 8.5 minutes from separation of the antenna to regain mobility. We believed relatively short time window of molting process in R. speratus kyushuensis may affect lengthy colony elimination time.

Background: Posterior capsule tightness (PCT), commonly seen in overhead athletes, is a soft tissue adaptation that is also noted in non-throwers. PCT is associated with scapular and humeral kinematic alterations, significant restriction of shoulder internal rotation (IR) range of motion (ROM), and significant scapular anterior tilting. Sleeper and cross-body stretches (CBS) are suggested for PCT and IR deficits, and have been modified since introduction. A novel modified sleeper stretch (NMSS) was designed in this study to prevent the risk of anterior translation of the humeral head. Though the effects of posterior shoulder stretching exercise have been widely studies, to the best of our knowledge, no previous studies have investigated the effectiveness of posterior shoulder exercises in decreasing scapular anterior tilting. Objects: To compare the immediate effects of two posterior shoulder stretching exercises (NMSS and CBS) on scapular anterior tilting and shoulder IR ROM. Methods: Thirty-two subjects with anteriorly tilted scapula and IR deficits [mean age: 24.3 ± 2.5 years; 15 males and 17 females] participated in this study. Subjects were randomly assigned to either the NMSS or CBS groups. Scapular anterior tilting (at rest and at shoulder 60° active IR) and shoulder IR ROM were measured before and immediately after intervention. Results: Scapular anterior tilting significantly decreased, while the shoulder IR ROM significantly increased in both groups. However, there was no significant group-by-time interaction effect or significant difference between the groups. Conclusion: Both stretching exercises were effective in restoring shoulder IR ROM and decreasing scapular anterior tilting.

A Forbush decrease (FD) is a depression of cosmic ray (CR) intensity observed by ground-based neutron monitors (NMs). The CR intensity is thought to be modulated by the heliospheric magnetic structures including the interplanetary coronal mass ejection (ICME) surrounding the Earth. The different magnitude of the decreasing in intensity at each NM was explained only by the geomagnetic cutoff rigidity of the NM station. However, sometimes NMs of almost the same cutoff rigidity in northern and southern hemispheres observe the asymmetric intensity depression magnitudes of FD events. Thus, in this study we intend to see the effects on CR intensity modulation of FD event recorded at different NMs due to different ICME propagation directions as an additional parameter in the model explaining the CR modulation. Fortunately, since 2006 the coronagraphs of twin spacecraft of the STEREO mission allow us to infer the propagation direction of ICME associated with the FD event in 3-dimension with respect to the Earth. We suggest the hypothesis that the asymmetric CR modulations of FD events are determined by the propagation directions of the associated ICMEs.

Background: Pain Neuroscience Education (PNE) is an educational approach that deals with the physiology of the nervous system as well as the pain system and refers to educating patients with chronic musculoskeletal disorders such as chronic back pain. Objectives: This study examined the effects of pain neuroscience education on patients with low back pain. Design: Systematic review. Methods: Electronic bibliographic databases of a regional information sharing system (RISS) and PubMed were searched to identify randomized controlled studies. In the final outcome, 43 publications were identified, and 13 studies met the inclusion criteria. Results: There were a total of 13 pain-related studies, including 11 studies using NPRS (VAS) and 2 studies using other pain measurement instruments. In NPRS, the effect size was 0.683, which had a medium effect size. In Roland morris disability questionnaire (RMDQ), the effect size was 0.544, which had a medium effect size. In Oswestry disability index (ODI), the effect size was 0.951, indicating a large effect size, but the confidence interval could not be obtained because there was only one study. Conclusion: Pain neuroscience education has positive effects on low back pain and disability index in related patients.

The evolvement in the microstructure and electrical properties of PAN-based carbon fibers during high-temperature carbonization were investigated. The study showed that as the heat treatment temperature increases, the change of carbon fiber resistivity around 1100 °C can be divided into two stages. In the first stage, the carbon content of the fiber increased rapidly, and small molecules such as nitrogen were gradually released to form a turbostratic of carbon crystal structure. The resistivity dropped rapidly from 3.19 × 10− 5 Ω·m to 2.12 × 10− 5 Ω·m. In the second stage, the carbon microcrystalline structure gradually became regular, and the electron movement area gradually became larger. At this time, the resistivity further decreases, from 2.12 × 10− 5 Ω·m to 1.59 × 10− 5 Ω·m. During carbonization, the tensile strength of carbon fiber first increased and then decreased. This is because the irregular and disordered graphite structure is formed first. As the temperature rose, the graphite layer spacing decreased and the grain thickness gradually increases. The modulus also gradually increased.

We report the use of face mask materials as a carbon precursor for the synthesis of multi- and single-walled carbon nanotubes (CNTs) in an open-loop chemical recycling process. Novel surgical mask precursors were suspended in toluene and injected into a chemical vapor deposition reactor previously optimized for CNT production using liquid injection. The CNTs were collected and characterized using resonant Raman spectroscopy, transmission electron microscopy (TEM) and scanning electron microscopy (SEM) before being turned into fibrils that were tested for electrical conductance. Once confirmed and repeated for statistical accuracy, a CNT-based Ethernet cable was manufactured and tested using iPerf3 for uplink and downlink speeds exceeding broadband standards worldwide. Radial breathing modes from Raman spectroscopy indicate single walled CNTs (SWCNTs) with diameters ranging from 0.8 to 1.55 nm and this matches well with TEM observations of SWCNTs with 1.5 nm diameter. This work pushes the horizon of feedstocks useful for CNT and SWCNT production in particular; this work demonstrates upcycling of materials fated for disposal into materials with positive net value and plenty of real-world applications.

A total of 31 bacterial strains were isolated from the Geum River basin in the Republic of Korea during our investigation of indigenous prokaryotic species. The isolated bacterial strains had high 16S rRNA gene sequence similarity (>98.7%) with those of validly published bacterial species, which have not been reported in Republic of Korea. The 31 bacterial strains were phylogenetically diverse and assigned to 4 phyla, 8 classes, 18 orders, 21 families, and 27 genera. At the genus level, the unreported species were affiliated with Kineococcus, Pedococcus, Rhodoluna, Salinibacterium, Rhodoluna, Arthrobacter, Williamsia, Nakamurella, Nocardioides of the class Actinobacteria, Patulibacter of the class Thermoleophilia, Pontibacter, Hymenobacter of the class Cytophagia, Flavobacterium of the class Flavobacteriia, Geomicrobium of the class Bacilli, Brevundimonas, Gellertiella, Rhizobium, Paracoccus, Taonella, Sphingomonas of the class Alphaproteobacteria, Burkholderia, Polaromonas, Hydrogenophaga, Chitinilyticum, Azospira, Zoogloea of the class Betaproteobacteria, and Pseudomonas of the class Gammaproteobacteria. The unreported bacterial species were further characterized by examining their morphological, cultural, physiological, and biochemical properties. The detailed descriptions of the 31 bacterial strains were provided.

The progress of science and technology has driven the development of the society, and the application of threedimensional simulation technology in all walks of life has greatly improved people's life. Maritime affairs is an important part of comprehensive transportation. The improvement of maritime supervision and service level is conducive to the construction of domestic first-class economic law enforcement system and international leading maritime management institutions. Now the application of 3D simulation technology to maritime supervision is studied, aiming to improve the quality and efficiency of supervision, make maritime supervision more convenient and have further guarantee. Maritime supervision of ship environment is often more troublesome than personnel management. In the process of monitoring and control, many uncontrollable environmental factors greatly increase the difficulty of supervision, among which the port environment is more complex, which is a difficulty of monitoring and control in maritime supervision. This paper uses MapInfo Professional, Win Topo, Multigen Creator and other operating software to construct the Qingdao port visual simulation environment. The port topographic cloud map of Qingdao Port was captured, and the collected image information was converted into data through MapInfo Professional and Win Topo software, and then modeled by Multigen Creator software. After completing the general terrain outline, the established simulation scene was made more realistic and realistic through some detail processing and optimization means. By describing the establishment of 3D simulation terrain in Qingdao Port, the application status of the simulation technology in ship environment and port management is reflected, which provides a reference for the deeper application of 3D simulation technology in maritime supervision.

This study investigated changes in psychological stress levels of 60 firefighters after participation in an eight-week Equine-Assisted Learning (EAL) program consisting of 16 sessions. The Korean versions of the Posttraumatic Diagnosis Scale (PDS-K), the Center for Epidemiological Studies Depression Scale (K-CESD), and the Difficulties in Emotional Regulation Scale (K-DERS) were used for measurements. Participants were divided into two groups according to level of posttraumatic stress symptoms (PTSS): the PTSS risk group and the PTSS non-risk group. Results showed that PDS-K, K-CESD, and K-DERS scores were significantly reduced after the program in the PTSS risk group. Significant reduction was also found in all sub-scales of PDS-K: re-experiencing, avoidance/emotional numbing, and hyperarousal. Moreover, in the PTSS risk group, there were greater improvements with significant group x time interactions. These findings suggest that EAL is effective in relieving PTSD and PTSD-related symptoms of firefighters with subsyndromal or more severe levels of PTSD.

본 연구는 한국 푸드뱅크 사업의 발전에 대한 법제적 접근을 취하고 있다. 양적 성장에의 기여와 질적 성장에의 걸림돌이라는 상반된 평가를 받고 있는 <식품등 기부활성화에 관한 법률>에 관한 문제점을 분석 하고 이에 대한 개선방안을 제시하고자 한다. 이를 위해 기부식품등 제공사업의 특징과 한계를 살펴보고 <식품등 기부활성화에 관한 법률>의 정의, 기부식품제공사업, 식품등 기부활성화 시책, 국가지원, 실태조사 등에 대해서 심층적으로 검토한다. 연구결과를 토대로 본 연구는 한국의 푸드뱅크 사업의 발전을 위하여 법률적 관점에서 다섯 가지를 제안한다. 첫째, <식품등 기부활성화에 관한 법률>은 기부식품등 제공사업에 관한 별도의 장을 마련하여 법 체계성을 확보할 필요가 있다. 둘째, 기부식품등 제공사업과 기부자·사업자 에 대하여 명확하게 정의할 필요가 있다. 셋째, 임의신고제에서 비롯된 운영의 질 저하를 막기 위하여 신고 제를 개선할 필요가 있다. 넷째, 기초기부식품등지원센터의 지정제를 도입할 필요가 있다. 다섯째, 국가 차 원의 정기적인 실태조사 조항을 신설할 필요가 있다. 이 같은 법률적 개선이 이루어진다면 기부식품등 제공 사업의 공공성과 책임성, 투명성, 전문성이 한층 제고될 수 있을 것이다.