In this study, commercial pellet type sorbents for the collection of CO2 from a local municipal waste incinerator were prepared and characterized in terms of adsorption efficiency by varying the operating conditions of a field process. The concentration of CO2 in the flue gas ranged from 8 to 10%, which entered the test packed bed. As a result of this experiment, the sorbent procured from A-company, which is mainly composed of calcium compounds, showed the highest adsorption efficiency. The regeneration efficiency was fairly low, however. It also was found that based on adsorption breakthrough time, the relatively low flow rate of 10 LPM into the bed allowed higher collection efficiency. The higher flow rate of 40 LPM, on the other hand, tended to decrease the retention of the adsorption.
This paper describes to evaluate the performance of ventilation as a change of CO2 concentration with ventilation rate under 35 occupants in a school classroom. Variations of the CO2 concentration as a function of time are measured at center point of classroom with air ventilation rates by the CO2 gas monitor. For 800 m3/h of ventilation rate in the classroom, the average CO2 concentration is 913 ppm. The ventilation rate is sufficient to meet acceptable indoor air quality (≤ 1,000 ppm of CO2, KS school standard) in the classroom of 35 students.
The volatile organic compounds(VOCs) emitted from raw garlic and Kimchee were analyzed with thermal desorption or purge & trap/gas chromatography/mass selective detection method. Very offensive compounds such as methyl allyl sulfide, dimethyl sulfide, dimethyl disulfide, diallyl sulfide, methyl allyl disulfide, diallyl disulfide and dimethyl trisulfide were detected, and among them, dimethyl disulfide and dimethyl trisulfide were confirmed to be generated during the precocity of Kimchee or emitted from the stuff of Kimchee other than the garlic. Malodorous compounds emitted from the garlic or Kimchee were detected in the breath of a Korean and the refregirator keeping Kimchee. It was confirmed that the disufides emitted from the garlic or Kimchee were major components of offensive odor in the alveolar air and the refregirator. It was clarified that heat process is very effective to reduce odorous VOCs in garlic or Kimchee.
This study is involved to develop new catalysts to decompose plastics, detergents and surfactants containing synthetic peptide bonds. As the first year research, the catalytic hydrolysis of amide bond in copper complex was accomplished. The hydrolysis reaction in aqueous solution was monitored by UV/VIS spectroscopy. As the pH of the solution is increased and the temperature is raised, the reaction rate increases. The reaction rate is observed as the first order kinetic behavior for the copper complex. The metal catalyzed hydrolysis mechanism is proposed via metal-hydroxide in the pH region of 5.5 to 6.3. The results of characterization of the catalytic reaction mechanism can be applied to develop new catalysts for peptide bond degradation in further research.