PS-N-heterocyclic carbene-metal catalysts were prepared using chloromethyl polystrene bead via two-step reaction. For the preparation of novel catalyst, imiazolium chloride salt provided ionic liquid moitery. The formation of metal complex with the polymer-supported N-heterocyclic carbene ligand was analyzed by XRD, FT-IR, SEM and EDX the reaction possibility was founded by viscosity measurement.