Composite-based piezoelectric devices are extensively studied to develop sustainable power supply and selfpowered devices owing to their excellent mechanical durability and output performance. In this study, we design a leadfree piezoelectric nanocomposite utilizing (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 (BCTZ) nanomaterials for realizing highly flexible energy harvesters. To improve the output performance of the devices, we incorporate porous BCTZ nanowires (NWs) into the nanoparticle (NP)-based piezoelectric nanocomposite. BCTZ NPs and NWs are synthesized through the solidstate reaction and sol-gel-based electrospinning, respectively; subsequently, they are dispersed inside a polyimide matrix. The output performance of the energy harvesters is measured using an optimized measurement system during repetitive mechanical deformation by varying the composition of the NPs and NWs. A nanocomposite-based energy harvester with 4:1 weight ratio generates the maximum open-circuit voltage and short-circuit current of 0.83 V and 0.28 A, respectively. In this study, self-powered devices are constructed with enhanced output performance by using piezoelectric energy harvesting for application in flexible and wearable devices.

Piezoelectric technology, which converts mechanical energy into electrical energy, has recently attracted drawn considerable attention in the industry. Among the many kinds of piezoelectric materials, BaTiO3 nanotube arrays, which have outstanding uniformity and anisotropic orientation compared to nanowire-based arrays, can be fabricated using a simple synthesis process. In this study, we developed a flexible piezoelectric energy harvester (f-PEH) based on a composite film with PVDF-coated BaTiO3 nanotube arrays through sequential anodization and hydrothermal synthesis processes. The f-PEH fabricated using the piezoelectric composite film exhibited excellent piezoelectric performance and high flexibility compared to the previously reported BaTiO3 nanotube array-based energy harvester. These results demonstrate the possibility for widely application with high performance by our advanced f-PEH technique based on BaTiO3 nanotube arrays.