Bismuth antimony telluride (BiSbTe) thermoelectric materials were successfully prepared by a spark plasma sintering process. Crystalline BiSbTe ingots were crushed into small pieces and then attrition milled into fine powders of about 300 nm ~ 2μm size under argon gas. Spark plasma sintering was applied on the BiSbTe powders at 240, 320, and 380˚C, respectively, under a pressure of 40 MPa in vacuum. The heating rate was 50˚C/min and the holding time at the sintering temperature was 10 min. At all sintering temperatures, high density bulk BiSbTe was successfully obtained. The XRD patterns verify that all samples were well matched with the Bi0.5Sb1.5Te3. Seebeck coefficient (S), electric conductivity (σ) and thermal conductivity (k) were evaluated in a temperature range of 25~300˚C. The thermoelectric properties of BiSbTe were evaluated by the thermoelectric figure of merit, ZT (ZT = S2σT/k). The grain size and electric conductivity of sintered BiSbTe increased as the sintering temperature increased but the thermal conductivity was similar at all sintering temperatures. Grain growth reduced the carrier concentration, because grain growth reduced the grain boundaries, which serve as acceptors. Meanwhile, the carrier mobility was greatly increased and the electric conductivity was also improved. Consequentially, the grains grew with increasing sintering temperature and the figure of merit was improved.
Ethyl cellulose(EC)와 platinum(II) acetylacetonate(Pt), rhodium(III)acetylacetonate(Rh)를 이용하여 용매증발법으로 고분자-금속 착체막을 제조하였다. 이때 최종 분리막의 제막조건을 최적화하기 위하여 금속염의 조성을 변화시켰다. (0.3-4.0 wt%). FTIR을 이용하여 EC-금속착체막을 분석하였으며 SEM을 이용하여 막의 구조를 관찰하였다. 그리고 산소, 질소, 이산화탄소, 메탄 가스들의 투과성능을 조사하였다. 금속염들은 모든 가스들의 선택도의 감소없이 투과도를 향상시킨다는 것을 알 수 있었다 그러나 Pt의 경우 산소와 질소가스의 투과성능에 더 영향이 있었으며, Rh은 이산화탄소와 메탄가스의 투과도에 더 영향이 있음을 알 수 있었다. EC-Pt 착체막의 경우에는, Pt의 산소와의 친화력특성에 기인하여 산소/질소의 선택도가 증가(37%)하는 것을 보여주었다.
본 연구는 동계 사료작물의 사료가치와 생산성을 높이기 위한 목적으로 겨울철에 일년생 두과작물 헤어리베치와 연맥을 3년간('99∼'01) 혼파 재배하였는데 도출된 결과를 요약하면 다음과 같다. 연맥과 헤어리베치의 혼파재배시 연맥과 헤어리베치의 출수기 및 개화기 등 생육은 큰 차이가 없었다. 사료가치를 보면 건물함량이 가을수확에서 15∼16%, 봄 수확에서 19∼20% 였고 조단백질 함량은 헤어리베치 단파시 30.1%로 가장 높았는데 연맥과 헤어리베치를 혼
The latest aerospace technology is important for the stable flight of a launch vehicle, but weather conditions on the day of launch are also one of the essential factors for successful launch campaign. If a launch vehicle is directly struck while preparing to take off from the launch pad on the day of launch or the electronic device are damaged by induced current during flight of the launch vehicle, this means launch failure and can lead to enormous national loss. Therefore, for a successful launch campaign, it is necessary to analyze the lightning detection characteristics of the Naro Space Center. In this study, the seasonal factors of the lightning that occurred over the Naro Space Center from 2003 to 2017, the influence of the polarity, and the correlation with the lightning intensity was confirmed. As a result, there was a high probability of intensive occurrence of multiple lightning strikes in summer, and a high proportion of positive (+) lightning strikes in winter. Lastly, in the distribution of the number of lightning strikes, an average of 2.0 to 2.5 negative (-) lightning strikes occurs in the coastal regions of the South and West Seas when one flash happens.