Friction stir spot welding (FSSW) is a solid-state joining process and a rapidly growing dissimilar material welding technology for joining metallic alloys in the automotive industry. Welding tool shape and process conditions must be appropriately controlled to obtain high bonding characteristics. In this study, FSSW is performed on dissimilar materials AA5052-H32 aluminum alloy sheet and SPRC440 steel sheet, and the influence of the shape of joining tool and tool insertion depth during joining is investigated. A new intermetallic compound is produced at the aluminum and steel sheets joint. When the insertion depth of the tool is insufficient, the intermetallic compound between the two sheets did not form uniformly. As the insertion depth increased, the intermetallic compound layer become uniform and continuous. The joint specimen shows higher values of tensile shear load as the diameter and insertion depth of the tool increase. This shows that the uniform formation of the intermetallic compound strengthens the bonding force between the joining specimens and increases the tensile shear load.

The synthesis of porous W by freeze-casting and vacuum drying is investigated. Ball-milled WO3 powders and tert-butyl alcohol were used as the starting materials. The tert-butyl alcohol slurry is frozen at –25oC and dried under vacuum at –25 and –10oC. The dried bodies are hydrogen-reduced at 800oC and sintered at 1000oC. The XRD analysis shows that WO3 is completely reduced to W without any reaction phases. SEM observations reveal that the struts and pores aligned in the tert-butyl alcohol growth direction, and the change in the powder content and drying temperature affects the pore structure. Furthermore, the struts of the porous body fabricated under vacuum are thinner than those fabricated under atmospheric pressure. This behavior is explained by the growth mechanism of tert-butyl alcohol and rearrangement of the powders during solidification. These results suggest that the pore structure of a porous body can be controlled by the powder content, drying temperature, and pressure.

The present study demonstrates the effect of magnetic pulse compaction and spark plasma sintering on the microstructure and mechanical property of a sintered W body. The relative density of green specimens prepared by magnetic pulse compaction increases with increase in applied pressure, but when the applied pressure is 3.4 GPa or more, some cracks in the specimen are observed. The pressureless-sintered W shows neck growth between W particles, but there are still many pores. The sintered body fabricated by spark plasma sintering exhibits a relative density of above 90 %, and the specimen sintered at 1,600 oC after magnetic pulse compaction shows the highest density, with a relative density of 93.6 %. Compared to the specimen for which the W powder is directly sintered, the specimen sintered after magnetic pulse compaction shows a smaller crystal grain size, which is explained by the reduced W particle size and microstructure homogenization during the magnetic pulse compaction process. Sintering at 1,600 oC led to the largest Vickers hardness value, but the value is slightly lower than that of the conventional W sintered body, which is attributed mainly to the increased grain size and low sintering density.

The effect of sublimable vehicles on the pore structure of Cu fabricated by freeze drying is investigated. The 5 vol% CuO-dispersed slurries with camphene and various camphor-naphthalene compositions are frozen in a Teflon mold at -25oC, followed by sublimation at room temperature. After hydrogen reduction at 300oC and sintering at 600 °C, the green bodies of CuO are completely converted to Cu with various pore structures. The sintered samples prepared using CuO/camphene slurries show large pores that are aligned parallel to the sublimable vehicle growth direction. In addition, a dense microstructure is observed in the bottom section of the specimen where the solidification heat was released, owing to the difference in the solidification behavior of the camphene crystals. The porous Cu shows different pore structures, such as dendritic, rod-like, and plate shaped, depending on the composition of the camphornaphthalene system. The change in pore structure is explained by the crystal growth behavior of primary camphor and eutectic and primary naphthalene. Keywords: Porous Cu, Pore structure

Sand casting 3D printing uses a binder jetting method to produce a mold having complicated shape by spraying a binder on sand coated with activator. Appropriate heat treatment process in sand mold fabrication can increase the degree of polymerization to improve flexural strength. However, long heat treatment of over 24 hours decreases flexural strength and reliability due to chemical bond decomposition through thermal degradation. The main role of the activator is to control the reaction rate between the polymer chains. As a result, when the activator composition is increased from 0.15 wt% to 0.25 wt%, the flexural strength is increased by 218 N/cm2. However, excess activator (0.40 wt%) has been shown to decrease reliability without increasing flexural strength. The main role of the binder is to control the flexural strength of the specimen. As the binder composition is increased from 2.00 wt% to 4.00 wt%, the flexural strength increases to about 255 N/cm2, indicating the maximum flexural strength increase. Finally, the reliability of the flexural strength of the fabricated specimens is evaluated by a Weibull plot. Weibull modulus calculations are used to evaluate the flexural strength reliability of the specimens, and maximum reliability value of 11.7 is obtained at 0.20 wt% activator composition. Therefore, it is confirmed that this composition has maximum flexural strength reliability.

A barley(Hordeum vulgare L.) cultivar 'Youjin' with hooded spike type having good silage quality was developed at National Institute of Crop Science, RDA in 2016. ‘Youjin’ showed both high yielding and cold resistance through the preliminary and advanced yield trials(PYT, AYT) from 2012 to 2013. We conducted regional yield trials(RYT) of ‘Youjin’ in six locations around Korea for three years from 2014 to 2016. It had erect plant type, growth habit of II, the green leaf and hooded awn type. In the paddy field its heading date was April 24 and the maturing date was May 25. Plant height was 99 cm and the number of spikes per m2 was 696. It has high rate of leaf blades, resistance to BaYMV(Barley Yellow Mosiac Virus) and good winter hardiness. The average dry matter of Youjin was about 17.2 MT ha-1 in the field. And feed quality of ‘Youjin’ was 10.6% of crude protein content, 24.8% of ADF(Acid Detergent Fiber), 43.5 % of NDF(Neutral Detergent Fiber), 69.1% of TDN(Total Digestible Nutrients). And also ‘Youjin’ had grade I of silage quality.

‘미한’은 추위 및 도복에 강한 다수성이면서 총체적성이 우수한 청보리 품종육성을 목표로 2001년 추위 및 도복에 강하며 초형이 양호한 ‘SB00T2064’를 모본으로, 양질다수성으로 총체적성이 우수한 ‘수원385호(IT215831)’를 부본으로 인공교배하였다.‘익산487호’로서 전국 6개소에서 2014년부터 2016년까지 지역적응시험을 거쳐 2016년에 육성되었다. ‘미한’은 기존 육성된 ‘영양’의 거친 망의 단점을 개선하여, 까락의 거치가 적은 반매끈망의 특성을 지니고 있다. 미한’은 직립 초형으로 파성은 IV정도로 영양보다는 추파성이 강하였다. 미한의 잎은 녹색이며, 엽폭은 중간정도이며, 엽이의 안토시아닌색은 없으며, 초장은 96㎝, ㎡당 경수는 665개로 표준품종인 ‘영양’ 보다 적었으나, 엽신 비율이 17.9%, 이삭비율은 52.2%로 높다. 답리작(전주 등 5개 지역 평균)에서 출수기는 4월 23일로 ‘영양’보다 3일 늦었으나, 황숙기는 5월 23일로 ‘영양’보다 1일 늦었다. ‘미한’은 내한성에 대해서는‘영양’보다 강하며, 흰가루병에는 약하며, 보리호위축병에 저항성을 나타냈다. 건물수량은 전작에서 13.9톤/ha으로 ‘영양’과 보다 5% 감수하였지만, 답리작에서 10.9톤/ha으로 ‘영양’과 같았다. 조사료 품질은 조단백질 함량이 10.3%로 ‘영양’에 비해 높았으며, ADF는 26.1%, NDF는 46.9%로 ‘영양’보다 높았으며 TDN이 68.2% ‘영양’보다 다소 낮았으나, 사일리지 품질등급은 I 등급으로 ‘영양’보다 우수하였다.

Core-shell structured nanoparticles are garnering attention because these nanoparticles are expected to have a wide range of applications. The objective of the present study is to improve the coating efficiency of gold shell formed on the surface of silica nanoparticles for SiO2@Au core-shell structure. For the efficient coating of gold shell, we attempt an in-situ synthesis method such that the nuclei of the gold nanoparticles are generated and grown on the surface of silica nanoparticles. This method can effectively form a gold shell as compared to the conventional method of attaching gold nanoparticles to silica particles. It is considered possible to form a dense gold shell because the problems caused by electrostatic repulsion between the gold nanoparticles in the conventional method are eliminated.

W-10 wt% Ti alloys that have a homogeneous microstructure are prepared by thermal decomposition of WO3-TiH2 powder mixtures and spark plasma sintering. The reduction and dehydrogenation behavior of WO3 and TiH2 are analyzed by temperature programmed reduction and a thermogravimetric method, respectively. The X-ray diffraction analysis of the powder mixture, heat-treated in an argon atmosphere, shows W- oxides and TiO2 peaks. Conversely, the powder mixtures heated in a hydrogen atmosphere are composed of W, WO2 and TiO2 phases at 600 ℃ and W and W-rich β phases at 800 ℃. The densified specimen by spark plasma sintering at 1500 ℃ in a vacuum using hydrogen-reduced WO3-TiH2 powder mixtures shows a Vickers hardness value of 4.6 GPa and a homogeneous microstructure with pure W, β and Ti phases. The phase evolution dependent on the atmosphere and temperature is explained by the thermal decomposition and reaction behavior of WO3 and TiH2.

This study aimed to determine the optimal harvesting time for wheat to make grain silage, in Honam region of Korea. We harvested wheat grain every third day from 30 to 42 days after heading (DAH). The moisture content decreased from 61.6% at 30 DAH to 42.8% at 42 DAH. Yield of wheat grain significantly increased from 30 to 42 DAH (p< 0.05). Yield at 39 DAH (3.46T/ha) was not significantly different from that at 42 DAH (p< 0.05). With respect to the feed value of wheat grain silage, the amount of crude protein, crude fiber, and crude ash was different by harvesting time (p< 0.05). However, the amount of total digestible nutrients (TDN) from 30 and 42 DAH was not significantly different. The pH of wheat grain silage from 30 to 42 DAH was between 3.8 and 4.5 and it was stable until 39 DAH (p< 0.05). The lactic acid content of wheat grain silage from 30 to 42 DAH decreased from 3.08% to 1.10%. With respect to moisture content, yield, feed value, and fermentation, the optimal harvesting time for wheat grain silage was 39 DAH.

'Dakyeong' (Avena sativa L.), a winter oats for forage use, was developed by the breeding team at National Institute of Crop Science, RDA in 2016. It was derived from a cross between ‘CI7505’(IT133304) and ‘Swan’(IT197920). Subsequent generations followed by the cross were handled in bulk and pedigree selection programs at Iksan and Jeonju, respectively. After preliminary and advanced yield test for 2 years, ‘SO2004009-B-B-10-8-3-9’, designated as a line name of ‘Gwiri91’, were subsequently evaluated for earliness and forage yield during 3 years in four parts such as Jeju (upland), Yesan (upland), Iksan (upland), and Jeonju (paddy), from 2014 to 2016, and finally named as ‘Dakyeong’. Cultivar ‘Dakyong’ has leaves of dark green color, thick diameter culm and long grain of brown color. Over 3 years, the heading date of ‘Dakyeong’ was about 5 days earlier than that of check cultivar ‘Samhan’ (April 30 and May 5, respectively), and their average forage dry matter yield harvested at milk-ripe stage was higher 12% (15.7 tone ha-1) than 14.0 tone ha-1 of check cultivar. Cultivar ‘Dakyeong’ was lower than the check cultivar ‘Samhan’ in terms of the protein content (6.1% and 7.0%, respectively) and total digestible nutrients (62.1%, and 62.5%, respectively), while the TDN yield was more than the check (7.79 tone ha-1 and 7.64 tone ha-1, respectively). Fall sowing cropping of ‘Dakyeong’ is recommended only in areas where average daily minimum mean temperatures in January are higher than -6°C, and it should not be cultivated in mountain areas, where frost damage is likely to occur.

Oats (Avena sativa L.), which are known as one of the forage crops of Korea, have good livestock palatability and are popular to cattle farmers because of their high dry matter. However, the cultivation of double cropping in the rice field was reluctant due to the late maturing for farmers to plant rice continuously. 'Hi-early', a winter oats for forage use, was developed by the breeding team at National Institute of Crop Science, RDA in 2016. It was derived from a cross between ‘517A2-121’(IT133383) and ‘CI7604’ (IT133379). Subsequent generations followed by the cross were handled in bulk and pedigree selection programs at Suwon, Iksan and Jeonju, respectively. After preliminary and advance yield test for 2 years, ‘SO2004015-B-B-23-1-3-7’, designated as a line name of ‘Gwiri92’, were subsequently evaluated for earliness and forage yield during 3 years in four parts such as Jeju (upland), Yesan (upland), Iksan (upland), and Jeonju (paddy), from 2014 to 2016, and finally named as ‘Hi-early’. Cultivar ‘Hi-early’ has the characteristics of medium leaves of green color, thick diameter culm, and medium grain of brown color. Over 3 years, the heading date of ‘Hi-early’ was about 9 days earlier than that of check cultivar ‘Samhan’ (April 26 and May 5, respectively). Average forage fresh yield of ‘Hi-early’ harvested at milk-ripe stage was similar to check cultivar (40.2 tone ha-1 and 40.0 tone ha-1, respectively), and dry matter yield also was similar to check cultivar (14.2 tone ha-1 and 14.0 tone ha-1, respectively). Cultivar ‘Hi-early’ was lower than the check cultivar ‘Samhan’ in terms of the protein content (6.2% and 7.0%, respectively) and total digestible nutrients (61.0%, and 62.5%, respectively), while the TDN yield was more than the check (7.91 tone ha-1 and 7.64 tone ha-1, respectively). Fall sowing cropping of ‘Hi-early’ is recommended only in areas where average daily minimum mean temperatures in January are higher than -6°C, and it should not be cultivated in mountain areas, where frost damage is likely to occur.

This study was conducted to investigate the feed value and silage quality according to storage period and film layers in whole crop oat silage. The crude protein content was increased in all silage during the storage periods compared to those before silage, under prolonged storage period slightly and the number of film layers of silage, six layer were higher than four layers, but no significant. NDF and ADF contents were also increased in all silage of storage duration compared to those before silage, but they was similar level between storage duration and number of film layers. TDN content was decreased of the storage duration. However, it was similar under the storage duration and the number of film layers. The pH value was decreased during prolonged storage period and six layers was lower than four layers depending on the film layers. In the organic acid contents, lactic acid and acetic acid were increased under the prolonged storage duration, and butyric acid was higher significantly(p<0.05), six layers of the film were showed higher lactic acid and lower butyric acid(p<0.05). Therefore, oat silage should be used within 6 months it was when treated with 4 layers, if considering the long-term storage, it is desirable to treat it with 6 layers or more.

A new barley(Hordeum vulgare L.) cultivar ‘Dachung’ having high forage yielding and good silage quality was developed at National Institute of Crop Science, RDA in 2015. This cultivar was derived from a cross of the ‘Sunwoo’ and ‘Keunalbori1ho’ in 2002. And it’s promising line showed both high yield and lodging resistance through the preliminary and advanced yield trials(PYT, AYT) at Iksan from 2010 to 2012. It was designated as the ‘Iksan479’. ‘Iksan479’ was conducted to regional yield trials(RYT) in six locations around Korea for three years from 2013 to 2015. And it was released as the name of ‘Dachung’. It has erect plant type, growth habit of IV and green leaf. In the paddy field its heading date was April 24 and maturing date was May 26, same day with ‘Youngyang’. Plant height of ‘Dachung’ was 99cm. Dachung’s spikes per m2 was 625. It has high rate of leaf blades, resistance to BaYMV(Barley Yellow Mosiac Virus) and better winter hardiness than that of ‘Youngyang’. The average dry matter of ‘Dachung’ was about 11.9 ton ha-1 in paddy field. And average feed quality of ‘Dachung’ was 9.0% of crude protein content, 31.3% of ADF (Acid Detergent Fiber), 54.4% of NDF (Neutral Detergent Fiber), 64.0% of TDN (Total Digestible Nutrients). ‘Dachung’ had grade I of silage quality. This cultivar would be suitable for the area above the daily minimum temperature of -8℃ in January in Korean peninsula.

This study was carried out to investigate the optimal harvesting time, feed value and fermentation quality of barley and wheat for the making of chopped whole crop silage substitute for formula feed. As a result, the moisture content of barley and wheat decreased with a late harvest, and barley progressed faster than wheat. The plant height was similar with harvesting time, and the number of spikes decreased with prolonged period after heading. The dry matter yield and TDN yield of barley harvested at 35 and 40 days after heading were significantly higher than those at 30 days after heading and wheat was significantly higher at 40 and 45 days than at 35 day after heading(P<0.05). Crude protein content of barley and wheat were increased with later harvesting time, and crude fiber, crude fat and crude ash were slightly decreased, but not statistically significant. NDF and ADF content of barley decreased with later harvesting time, and those showed similar level in wheat. TDN content of barely was slightly increased but there was no difference in wheat. Comparing the effects of fermentation on feed value of chopped whole crop silage, the approximate compositions were slightly increased after fermentation, but the difference was not significant. Fermentations resulted in increasing the pH value of barley silage with late harvesting time, but decreasing the lactic acid content(p<0.05). A pH value of wheat silage showed similar level in different harvest time, and lactic acid content was decreased. Considering the quantity and quality of fermentation, barley and wheat can be used for making chopped silage of whole crop silage when they were harvested at 35 days and 40~45 days after heading, respectively.

An optimum route to fabricate a hybrid-structured W powder composed of nano and micro size powders was investigated. The mixture of nano and micro W powders was prepared by a ball milling and hydrogen reduction process for WO3 and W powders. Microstructural observation for the ball-milled powder mixtures revealed that the nano-sized WO3 particles were homogeneously distributed on the surface of large W powders. The reduction behavior of WO3 powder was analyzed by a temperature programmed reduction method with different heating rates in Ar-10% H2 atmosphere. The activation energies for the reduction of WO3, estimated by the slope of the Kissinger plot from the amount of reaction peak shift with heating rates, were measured as 117.4 kJ/mol and 94.6 kJ/mol depending on reduction steps from WO3 to WO2 and from WO2 to W, respectively. SEM and XRD analysis for the hydrogen-reduced powder mixture showed that the nano-sized W particles were well distributed on the surface of the micro-sized W powders.

The effect of the mixing method on the characteristics of hybrid-structure W powder with nano and micro sizes is investigated. Fine WO3 powders with sizes of ~0.6 μm, prepared by ball milling for 10 h, are mixed with pure W powder with sizes of 12 μm by various mixing process. In the case of simple mixing with ball-milled WO3 and micro sized W powders, WO3 particles are locally present in the form of agglomerates in the surface of large W powders, but in the case of ball milling, a relatively uniform distribution of WO3 particles is exhibited. The microstructural observation reveals that the ball milled WO3 powder, heat-treated at 750oC for 1 h in a hydrogen atmosphere, is fine W particles of ~200 nm or less. The powder mixture prepared by simple mixing and hydrogen reduction exhibits the formation of coarse W particles with agglomeration of the micro sized W powder on the surface. Conversely, in the powder mixture fabricated by ball milling and hydrogen reduction, a uniform distribution of fine W particles forming nano-micro sized hybrid structure is observed.

This experiment was conducted to obtain information of feed value and fermentative quality of wheat cultivar, ‘Taejoong’ to confirm availability as a whole crop silage. As a result, the heading date of ‘Teajoong’ is April 27, and plant height is longer than whole crop barley, ‘Youngyang’ or whole crop wheat, ‘Cheongwoo’, spike length are also large, fresh and dry matter yield are also high. In case of feed value, ‘Taejoong’ had higher crude protein content than whole crop barley, ‘Youngyang’ or whole crop wheat, ‘Cheongwoo’, lower NDF and ADF contents, and significantly higher digestible nutrient contents(p<0.05). In case of fermentation qulity, pH of ‘Taejoong’ was 4.2, and lactic acid content was lower than ‘Cheongwoo’ silage and significantly higher than ‘Youngyang’ silage(p<0.05). Acetic acid content was significantly lower than ‘Youngyang’ and ‘Cheongwoo’ silage(p<0.01), butyric acid content was significantly lower than that of ‘Youngyang’ silage (p<0.05). The final Flieg's score showed that ‘Taejoong’ silage was the best. Also income of ‘Taejoong’ improved than ‘Youngyang’ or ‘Cheongwoo’. Therefore, ‘Taejoong’ is considered sufficiently available as whole crop for forage.

The sol-gel method is the simplest method for synthesizing monodispersed silica particles. The purpose of this study is to synthesize uniform, monodisperse spherical silica nanoparticles using tetraethylorthosilicate (TEOS) as the silica precursor, ethanol, and deionized water in the presence of ammonia as a catalyst. The reaction time and temperature and the concentration of the reactants are controlled to investigate the effect of the reaction parameters on the size of the synthesized particles. The size and morphology of the obtained silica particles are investigated using transmission electron microscopy and particle size analysis. The results show that monodispersed silica particles over a size range of 54-504 nm are successfully synthesized by the sol-gel method without using any additional process. The nanosized silica particles can be synthesized at higher TEOS/H2O ratios, lower ammonia concentrations, and especially, higher reaction temperatures.