This study was performed to identify the state of the exposure and characteristics of pollutants by each process at 4 casting sites located in Gyeongsang-do from April to November 2013. The concentrations of methanol, crystallized silica glass, formaldehyde and phenol were analyzed by different process - casting process, molding process, core process, and shakeout & finishing process. The highest concentration of methanol was found in casting and molding process, whereas the highest concentration of crystalline quartz(Silica) was observed in core process. The most oxidized steel dusts and the highest concentration of fume were found in shakeout & finishing process. As a result of this study, those labors working at the casting site were found to be constantly exposed to various forms of hazardous chemicals; therefore, it is considered that this is the time to manage and plan how to reduce them. In addition, it is required to thoroughly manage the local exhauster, and improve the process and working environment to reduce various forms of hazardous chemicals.
The air quality data is important for understanding and analyzing a surrounding influence. In that light, it is positively necessary for a propriety assessment to determine a location of the air quality monitoring sites. In this study, the climate analysis about temperature and wind, using the meteorological data in the Pohang, is conducted to do that. In the next stage, we distinguished the wind by east-west or north-south component, which has less correlation than temperature, analyzed and divided the wind sector. As the result, the wind circumstance of the Pohang is divided into major 5 wind sector; that is the urban area, the northeast coastal area, the east ocean and the west mountainous area. We think that an analysis on detailed wind sector by utilizing the numerical simulation is needed.
Sorbents of calcined limestone and oyster particles having a diameter of about 0.63㎜ were exposed to simulated fuel gases containing 5000ppm H2S for temperatures ranging from 600 to 800℃ in a TGA (Thermalgravimetric analyzer). The reaction between CaO and H2S proceeds via an unreacted shrinking core mechanism. The sulfidation rate is likely to be controlled primarily by countercurrent diffusion through the product layer of calcium sulfde(CaS) formed. The kinetics of the sorption of H2S by CaO is sensitive to the reaction temperature and particle size, and the reaction rate of oyster was faster than the calcined limestone.