Pressure retarded osmosis (PRO) processes can be implemented on a number of water types, using different technologies and achieving various power outcomes. In this study, Sewage facility effluent was used for feed solution of PRO and synthetic NaCl water for draw solution. This study was conducted to investigate effect of water quality of pretreatment on power density and flux decline in PRO process. The results show that organic and particulate foulants have to be removed for more stable operation. Flourescence technique with EEM enables to investigate the chemical properties of aquatic organic matter by extracting spectral information. Humic/fulvic matters and soluble microbial by-products were analyzed as the most affecting factors on the PRO performance. As a result of analyzing the whole system based on the energy consumption of the unit process, specific energy consumption(SEC) of the applicable technology for PRO pre-treatment should be about 0.2 kWh/m3 or less.
The Pressure Retarded Osmosis (PRO) is the next generation desalination technique and is considered as a eco-friendly energy. This was conducted to evaluate the effect of the temperature and pressure on the PRO performance. The flux of the permeation was measured under different operating conditions and estimated the power density. An improvement of PRO performance is depend on increasing solution temperature and optimum pressure. The effect of increasing feed solution temperature has stronger impact on the PRO performance comparing to the draw solution temperature. The reason of the results was due to the change of osmotic power, viscosity, water permeability and structure parameter(s).
본 연구는 SWRO/PRO 조합공정에서 PRO 공정 유입수로써 적합한 유입수질 조건과 전처리 기술을 알아보고자 하였다. 실험에 사용된 유입수로는 P시의 하수처리장 방류수를 사용하였으며, 유도용매는 역삼투막 농축수를 활용하였고, 이때 사용한 PRO막은 Toray사의 CTA재질막을 사용하였다. 본 연구에서 응집-침전, 모래여과, DMF, 활성탄여과, 정밀여과공정, 역삼투공정 등 총 6가지 전처리공정을 선정하여 평가하였고, PRO 공정 성능에 영향을 크게 주는 것으로 확인하였다. 향후 SWRO/PRO 조합공정에서 안정적인 에너지 절감 효과를 기대할 수 있는 최적 공정을 도출할 계획이다.