열가소성 고분자 복합재료 개발을 위하여 매트릭스 수지로는 폴리프로필렌섬유(PP)를 사용하고 유기계 강화소재로 폴리비닐알코올(비닐론, VF), 아라미드(케블라-49, KF) 및 폴리아미드섬유(PAF)등을 사용하였다. 복합매트제조장치로서 복합매트를 제조하고 가열.압축하여 고분자 복합재료를 성형하였다. 제조한 고분자 복합재료의 형태학, 유변학적 및 기계적특성 등을 측정하였다. 형태학에서 미트릭스와 강화섬유 간의 젖음성은 강화섬유의 함량이 증가함에 따라 감소하는 경향을 보였다. PAF/PP와 VF/PP 복합재료에 대한 점성도는 낮은 주파수 영역에서 강화섬유의 함량이 증가됨에 따라 증가하였으나, 높은 주파주 영역에서 5-20wt%로 강화된 복합재료는 매트릭스인 PP에 근접하게 감소된 점성도를 나타냈다. 기계적 특성은 강화 섬유의 함량에 따라 변하였으며, VF/PP 및 KF/PP 복합재료가 PAF/PP 계에 비해 우수한 현상을 보였다.

At present research on mining backfill materials is being carried out to prevent ground subsidence and breaking by underground cavern of exhausted mines. However, backfill materials can cause secondary environmental issues such as ground pollution. To solve these issues, liner and cover materials are constructed before backfill materials constructed, to inhibit toxic substances form moving to the surroundings. Liner and cover materials, however, should have an accelerating performance after construction and when the accelerating performance is degraded, the work efficiency can be lowered, and the construction cost can be increased, by many rebound content. Therefore, this study develops mining liner and cover materials, and evaluates their accelerating performance and physical properties of liner and cover materials by types and content of accelerating agent. In case of aluminate accelerating agent, it is mixed with more than 5% of liner and cover materials(binder/ratio); thus an accelerating performance satisfying Korean Industrial Standards(KS) occurs, and in case of alkali-free accelerating agent, when it is mixed with more than 7%(binder/ratio), accelerating performance satisfying KS occurs. The more the accelerating agent capacity increases, the more compressive strength decreases. In addition, it is confirmed that compressive strength of aluminate accelerating agent is more degraded than compressive strength of the alkali-free accelerating agent. It is also confirmed that drying shrinkage stability of the alkali-free accelerating agent is better than the drying shrinkage stability of the aluminate accelerating agent.

A Controlled Low-Strength Materials (CLSM) is suitable for mine backfilling because it does not require compaction owing to it high fluidity and can be installed quickly. Therefore, a CLSM utilizing CO2-solidified Circulating Fluidzed Bed Combustion (CFBC) coal ash was developed and it’s properties were investigated, since. CO2-solidification of CFBC coal ash can inhibit exudation of heavy metals. The chemical composition and specific surface area of Pulverized coal Combustion fly ash and CFBC fly ash were analyzed. The water ratio, compressive strength and length change ratio of CLSM were confirmed. The water ratios differed with the specific surface area of the CLSM. It was confirmed that the porosity of CLSM affected its compressive strength and length change ratio.