Flexible dye-sensitized solar cells using binder free TiO2 paste for low temperature sintering are developed. In this paste a small amount of titanium gel is added to a paste of TiO2 nanoparticle. Analysis of titanium gel paste prepared at 150 ℃ shows that it has a pure anatase phase in XRD and mesoporous structure in SEM. The formation of the titanium gel 1- 2 nm coated layer is confirmed by comparing the TEM image analysis of the titanium gel paste and the pristine paste. This coating layer improves the excited electron transfer and electrical contact between particles. The J-V curves of the organic binder DSSCs fabricated at 150℃ shows a current density of 0.12 mA/cm2 and an open-circuit voltage of 0.47 V, while the titanium gel DSSCs improves electrical characteristics to 5.04 mA/cm2 and 0.74 V. As a result, the photoelectric conversion efficiency of the organic binder DSSC prepared at low temperature is as low as 0.02 %, but the titanium gel paste DSSCs has a measured effciency of 2.76%.
The improvement of dispersion stability for the primary polishing slurry in a CMP process is achieved to prevent defects produced by agglomeration of the slurry. The dispersion properties are analyzed according to the physical characteristics of each silica sol sample. Further, the difference in the dispersion stability is confirmed as the surfactant content. The dispersibility results measured by Zeta potential suggest that the dispersion properties depend on the content and size of the abrasive in the primary polishing slurry. Moreover, the optimum ratio for high dispersion stability is confirmed as the addition content of the surfactant. Based on the aforementioned results, the long-term stability of each slurry is analyzed. Turbiscan analysis demonstrates that the agglomeration occurs depending on the increasing amount of surfactant. As a result, we demonstrate that the increased particle size and the decreased content of silica improve the dispersion stability and long-term stability.