Kori Unit 1 was permanently shut down in 2017 and is currently being prepared for decommissioning. Decommissioning waste generated during the decommissioning of a nuclear power plant has the characteristic of being generated in large quantities over a short period. Therefore, if proper management is not carried out, abnormal situations (i.e., unauthorized disposal, diversion, etc.) may occur. According to IAEA General Safety Report Part 6, radioactive waste shall be managed for all waste streams in decommissioning. This means ensuring that all waste streams are managed by the recorded inventory of all decommissioning waste and verifying that the recorded inventory is reasonable. The radioactive waste management has been managed in units such as mass and radioactivity. However, in the case of decommissioning waste, the amount is very large, so management by radioactivity is expected to have limitations. Therefore, in this study, a simple test was conducted to verify the decommissioning waste generated by a hypothetical scenario by mass. In this study, establish a scenario assuming various flows of decommissioning waste expected to be generated and calculate the expected inventory of decommissioning waste using Microsoft Excel. Specifically, using “Material Unaccounted For” (MUF), a material balance equation in IAEA Services Series 15, Nuclear Material Accounting Handbook, the error inventory was calculated as the difference between the physical inventory of decommissioning waste in the area and the ending inventory. We propose a simple test scenario to verify the flow of decommissioning waste by verifying that the error inventory reasonably matches the set allowable error. This study aims to verify the inventory of decommissioning waste using the material balance methodology used for nuclear material accounting. It is expected that the safety and reliability of the nuclear power plant decommissioning process can be secured by verifying that the total inventory of equipment before decommissioning and the inventory of remaining equipment and decommissioning waste after decommissioning are reasonably consistent.

The solid-state chemistry of uranium is essential to the nuclear fuel cycle. Uranyl nitrate is a key compound that is produced at various stages of the nuclear fuel cycle, both in front-end and backend cycles. It is typically formed by dissolving spent nuclear fuel in nitric acid or through a wet conversion process for the preparation of UF6. Additionally, uranium oxides are a primary consideration in the nuclear fuel cycle because they are the most commonly used nuclear fuel in commercial nuclear reactors. Therefore, it is crucial to understand the oxidation and thermal behavior of uranium oxides and uranyl nitrates. Under the ‘2023 Nuclear Global Researcher Training Program for the Back-end Nuclear Fuel Cycle,’ supported by KONICOF, several experiments were conducted at IMRAM (Institute of Multidisciplinary Research for Advanced Materials) at Tohoku University. First, the recovery ratio of uranium was analyzed during the synthesis of uranyl nitrate by dissolving the actual radioisotope, U3O8, in a nitric acid solution. Second, thermogravimetric-differential thermal analysis (TG-DTA) of uranyl nitrate (UO2(NO3)2) and hyper-stoichiometric uranium dioxide (UO2+X) was performed. The enthalpy change was discussed to confirm the mechanism of thermal decomposition of uranyl nitrate under heating conditions and to determine the chemical hydrate form of uranyl nitrate. In the case of UO2+X, the value of ‘x’ was determined through the calculation of weight change data, and the initial form was verified using the phase diagram for the U-O system. Finally, the formation of a few UO2+X compounds was observed with heat treatment of uranyl nitrate and uranium dioxide at different temperature intervals (450°C-600°C). As a result of these studies, a deeper understanding of the thermal and chemical behavior of uranium compounds was achieved. This knowledge is vital for improving the efficiency and safety of nuclear fuel cycle processes and contributes to advancements in nuclear science and technology.