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        검색결과 2

        1.
        2025.12 KCI 등재 구독 인증기관 무료, 개인회원 유료
        The high theoretical capacity of transition metal-based compounds makes them promising candidates for lithium-ion battery (LIB) anodes. Among them, iron selenide (FeSe2) has attracted considerable interest because of its excellent electrical conductivity and superior lithium storage capacity. However, pristine FeSe2 suffers from rapid capacity fading and structural instability during repeated cycling. Thus, this study used a facile solvothermal method to synthesize a FeSe2@rGO composite with enhanced structural integrity and electrical conductivity. By incorporating reduced graphene oxide (rGO), the composite demonstrated improved charge transfer kinetics and mechanical robustness. Morphological and structural characterizations were performed using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy analyses (XPS), which confirmed the successful formation of the composite and its uniform distribution. Electrochemical properties were evaluated using cyclic voltammetry (CV), galvanostatic charge-discharge, long-term cycling, and electrochemical impedance spectroscopy. The optimized FeSe2@rGO electrode delivered a high reversible capacity of 971.95 mAhg-1 at 500 mAg-1 after 350 cycles. The underlying charge storage mechanism was investigated using scan rate-dependent CV, which revealed a dominant capacitivecontrolled contribution at higher scan rates. The study findings indicate that the FeSe2@rGO composite can serve as a high-performance anode material with excellent cycling stability and rate capability, providing a viable strategy for the development of advanced LIBs.
        4,000원
        2.
        2022.10 KCI 등재 구독 인증기관 무료, 개인회원 유료
        Carbon fibers (CFs) are considered promising composite materials for various applications. However, the high cost of CFs (as much as $26 per kg) limits their practical use in the automobile and energy industries. In this study, we developed a continuous stabilization process for manufacturing low-cost CFs. We employed a textile-grade polyacrylonitrile (PAN) fiber as a low-cost precursor and UV irradiation technique to shorten the thermal stabilization time. We confirmed that UV irradiation on the textile-grade PAN fibers could lower the initial thermal stabilization temperature and also lead to a higher reaction. These resulted in a shorter overall stabilization time and enhancement of the tensile properties of textilegrade PAN-based CFs. Our study found that only 70 min of stabilization time with UV irradiation was required to prepare textile-grade PAN-based low-cost CFs with a tensile strength of 2.37 ± 0.22GPa and tensile modulus of 249 ± 5 GPa.
        4,000원