Sintering behavior of the Fe-0.8Mn-0.5C powder system was studied on the specimens with a density of ~7.0 g/cc sintered at 11200C for 30 min in a gas mixture of 7%H2/93%N2 with the inlet dew point of -600C. During the atmosphere monitoring (CO/CO2-content and dew point) was showed, that carbothermical reduction occurs in two different temperature ranges; three peaks of dew point profile also can be distinguished during sintering cycle as well. Following sintering the Mn-content distribution and microstructures around the Mn-source were micro-analytical evaluated; the results showed that manganese travels through porous iron matrix up to ~60 μm.