본 논문은 회분식 반응기에서 습식 산화법으로 합성한 칼륨 페레이트(VI)에 의한 난분해성 아조 염료Reactive Black 5의 분해 과정을 연구하는 것을 목적으로 한다. 수용액에서 RB5의 분해는 pH, Ferrate (VI) 투입량, 초기 농도, 수용액 온도 등 다양한 변수의 조건에서 연구되었다. RB5 경우에는 최대 분해 효율은 pH 7.0에서 63.2%가 달성되었으며, 이 실험 조건에서 얻은 kapp 값은 190.49 M-1s-1 으로 나타났다. 온도 또한 가장 중요한 매개 변수 중 하나로 연구되었으며, 그 결과로부터 온도(45°C까지)를 증가시키면 페레이트(VI)에 의한 아조 화합물 염료의 분해 효율이 증가하고, 온도가 45°C를 초과하면 분해 효율이 저하되는 것으로 나타났다.

The study of water environment system using a multivariate analysis in Changnyeong-Haman weir section has been conducted. The purpose of this study is to establish better understanding related water qualities in the Changnyeong-Haman weir section which can provide useful information. The data were consisted of water quality data and algae data including WT(water temperature), pH, DO, EC, COD, SS, T-N, NH3-N, T-P, PO4-P, Chl-a, TOC, d-silica, t-silica, Cyanobacteria, Diatoms, and Green algae. Statistical analyses used in this study were correlation analysis, principal components, and factor analysis. According to correlation analysis on COD and TOC, it revealed that the each value of correlation coefficient was 0.843. On the other result, a negative correlation was observed between diatoms and d-silica. Furthermore, the results of principal component analysis to the overall water quality were classified into four main factors with contribution rate 81.071%.

In this study, water quality levels were classified and water quality indices were calculated and analysed by using the water quality components of living environmental standards monitored 10 years (2008 ~ 2017) at four stations in the West Nakdong River. As a result of analyzing the monthly variation of the water quality components of the living environmental standards, the water quality in the West Nakdong River was worse downstream than upstream, and pollution at the WNR3 located in the downstream of the Jomangang was the most serious. As a result of classification of water quality levels, BOD and COD levels were the lowest, so water quality pollution in the West Nakdong River was found to be highly influenced by organic matters. The water quality index was the lowest in July and August at four stations, so water quality is showing the worst in summer. As a result of analyzing the correlation between the water quality components and the water quality index, the correlation between the TOC and the water quality index was high in the four stations, and the water quality index in the West Nakdong River was dominated by organic matters and nutrients.

In this study, monthly average values of BOD, COD, and TOC observed for 10 years (2008–2017) in the Nam River were estimated, and monthly variations of BOD, COD, and TOC were analyzed. Monthly average COD was always higher than monthly average BOD; monthly average TOC was high from June to September when rainfall was high. Monthly correlation coefficients between BOD and COD ranged from 0.57 to 0.94, those between BOD and TOC from 0.45 to 0.93, and those between COD and TOC from 0.75 to 0.93. The correlation coefficients were high from November to February when rainfall was low. Regression analyses for monthly average water quality data of the Nam River classified into dry season (October to April) and wet season (May to September) were conducted. Correlation coefficients were higher in the dry season than those in the wet season, and the determination coefficients of linear regression functions for BOD and COD with TOC were also higher in the dry season than those in the wet season. From this study, it can be concluded that it is appropriate to use monthly data to analyze the correlations among BOD, COD, and TOC in the stream. To analyze the relationship between TOC flowing into the stream and BOD/COD, it was found that seasonal characteristics should be considered.

Herein, we analyzed the spatial and temporal variation of DO (dissolved oxygen), BOD (biochemical oxygen demand), and COD (Chemical Oxygen Demand) with the monthly mean observed data for 10 years (2008~2017) in the main stream of the Nakdong River. The water quality of the stations declined in a downstream direction, with the BOD and COD showing their highest values at the ST5 station. From the analysis of the correlation of water quality components at 10 stations, the correlation coefficient between the DO and water temperature was more than –0.90, and that between BOD and Chl-a was 0.48~0.85, and that between COD and TOC was more than 0.65 except for the ST5 and ST10 stations. From the regression analysis using data collected from all stations, the water temperature and DO decreased linearly with a coefficient of determination of 0.90, and the Chl-a and BOD could be described by increasing power functions with a coefficient of determination of 0.83. The TOC and COD followed increasing logarithm functions with a coefficient of determination of 0.58. The TOC efficiency at the 10 stations was estimated and the average efficiencies of BOD and COD were 15.5~36.3% and 57.4~89.6%, respectively.

In this study, the water quality components (pH, BOD, COD, TOC, SS, DO, TP) and the water quality, observed for 10 years (2008~2017) in the five tributaries of the Nakdong River with the highest flow rates, were analyzed. Monthly levels of the water quality components were estimated and regression functions were used to quantitatively explain the changes in the BOD and COD components, with respect to the TOC components. The results of analyzing the water quality levels in terms of the living environmental standards show that the lowest water quality was observed midstream (ST-3) and the highest water quality was observed upstream (ST-1 and ST-2). The regression function was estimated to be a linear function in all five tributaries, and the goodness of fit of the function was high upstream (ST-2), midstream (ST-3), and downstream (ST-4). According to the regression analysis using the observation data from 2008~2017, we found that the consumption of dissolved oxygen increased with an increase in organic matter in the major tributaries of the Nakdong River.