This study summarizes the relations among PM2.5 concentration, water-soluble ions concentration, metallic element Components characteristics and SPSS in negative ion and metallic element of PM2.5 particle in Miryang.(By the urban area, the industrial complex area and the suburban area according to the season) PM2.5 concentration of total 72 samples collected from 3 sites turned out to range from 3.47 to 34.7 μg/m3 , and the average concentration was the suburban area-the kin nup(16.00 μg/m3 ) > the urban area-the roof of the old Miryang university(10.32 μg/m3 ) > the industrial complex-Sapo industrial complex(10.29 μg/m3 ). In particular, the suburban area had PM2.5 concentration 1.5 times those of urban area, industrial complex. It was thought although the site was suburban and farm-side without pollutants around, it had a higher concentration value influenced by external factors including the brickyard, small-scale incinerator, driving range construction, construction on the Daegu-Busan express and the widening of the four-lane road between Miryang-Anyang nearby. As for water-soluble ions among PM2.5 particle collected in Miryang area, SO42− accounted for 60% and NO3−, was 30% in spring and summer. And NO3− accounted for 50% and SO42− was 35% in fall and winter. The AI value of metallic Components among PM2.5 particle collected in Miryang area had a high value influenced by the apartment complex construction and the extension work of road. The industrial complex area had Zn concentration 3 times, and Fe concentration 2 times those of urban area and suburb area. When it comes to the relation with metallic elements in urban area, the highest coefficient of correlation was between Cr-Fe with 0.85, and Pb-Cd turned out in the reverse correlation. Among metallic elements, the coefficients of correlation between Zn and Cr, Mn, Fe, NI were high in industrial complex area. The highest coefficient of correlation was between Mn-Zn with 0.88, meanwhile Ni and Cu, Cd turned out in the reverse correlation in the suburb area. These coefficients of correlation are attributed to the difference in pollutant sources, rather than difference in pollutant and non-pollutant.

The emissions characteristics of particulate matters(PM) according to the types of wastes from industrial waste incinerator of 800 kg/hr treatment capacity were investigated. For this study, the incinerate waste are as follows; waste resin, waste wood, waste urethane, waste gunny, and waste paper. The particulate samples were collected to be emitted in stack and air pollution control(both cyclone and bag filter). In stack, the concentrations of PM were in the range of 2.61 to 26.51 ㎎/S㎥ and the major chemical species were C, Si, Cl, K, Na, Ca in all the wastes. In cyclone fly ash, the mean content of heavy metal were in the order of Fe > Zn > Pb > Cu > Mn > Cr > Ni > Cd > As > Hg and the heavy metal content of waste resin were Zn 34,197.5 mg/kg, Fe 27,587.6 mg/kg, Pb 6,055.8 mg/kg, respectively. In bag filter fly ash, the mean content of heavy metal were in the order of Zn > Pb > Fe > Cu > Mn > Cd > Cr > Ni > As > Hg and the heavy metal content of waste wood were Pb 36,405.2 mg/kg, Fe 15,762.9 mg/kg, Cu 9,989.5 mg/kg, Cd 2,230.1 mg/kg, respectively. Comparing the heavy metal content of both cyclone and bag filter, in cyclone, the Cr, Fe, Ni content were higher than in bag filter and the Cd, Cu, Hg content were lower than in bag filter.

Research results for the pressure drop variance depending on operation conditions such as change of inlet concentration, pulse interval, and face velocity, etc., in a pulse air jet-type bag filter show that while at 3kg/cm2 whose pulse pressure is low, it is good to make an pulse interval longer in order to form the first layer, it may not be applicable to industry because of a rapid increase in pressure. In addition, the change of inlet concentration contributes more to the increase of pressure drop than the pulse interval does. In order to reduce operation costs by minimizing filter drag of a filter bag at pulse pressure 5kg/cm2, the dust concentration should be minimized, and when the inlet dust loading is a lower concentration, the pulse interval in the operation should be less than 70 sec, but when inlet dust loading is a higher concentration, the pulse interval should be below 30 sec. In particular, in the case that inlet dust loading is a higher concentration, a high-pressure distribution is observed regardless of pulse pressure. This is because dust is accumulated continuously in the filter bag and makes it thicker as filtration time increases, and thus the pulse interval should be set to below 30 sec. If the equipment is operated at 1m/min of face velocity, while pressure drop is low, the bag filter becomes larger and thus, its economics are very low due to a large initial investment. Therefore, a face velocity of around 1.5 m/min is considered to be the optimal operation condition. At 1.5 m/min considered to be the most economical face velocity, if the pulse interval increases, since the amount of variation in filter drag is large, depending on the amount of inlet dust loading, the operation may be possible at a lower concentration when the pulse interval is 70 sec. However, for a higher concentration, either face velocity or pulse interval should be reduced.

Comparing predicted PCDF isomer patterns with those obtained from a municipal waste incinerator assessed the role of two-phenol condensation pathways in the formation of PCDFs. Complete PCDF homologue and isomer distributions were obtained from a Fluidized Bed Incinerator (FBI). Two-phenol condensation model, dependent only on the distributions of phenols, was developed to predict the PCDF congeners produced from phenol precursors. R-squared values from linear correlations are presented for the dichlorinated through hexachlorinated isomer distributions between measured and predicted. They range from 0.003 to 0.1 for the dichlorinated through hexachlorinated isomer sets. Agreement between predicted and measured PCDF isomer distributions was very poor for all homologues. Two-phenol condensation pathways are not likely to be the predominant pathways in the formation of PCDF in a FBI. However, dibenzofuran (DF) is likely to be produced from a condensation of two phenols. This work demonstrates the use of PCDF homologue and isomer patterns for testing PCDF formation mechanism from two-phenol condensation pathways in municipal waste incinerators.