Activated carbon (AC) was synthesized from rice husks using the chemical activation method with KOH, NaOH, a combination of (NaOH + Na2CO3), and a combination of (KOH + K2CO3) as the chemical activating reagents. The activated carbon with the highest surface area (around 2000m2/g) and high porosity, which allows the absorption of a large number of ions, was applied as electrode material in electric double layer capacitors (EDLCs). The AC for EDLC electrodes is required to have a high surface area and an optimal pore size distribution; these are important to attain high specific capacitance of the EDLC electrodes. The electrodes were fabricated by compounding the rice husk activated carbons with super-P and mixed with polyvinylidene difluoride (PVDF) at a weight ratio of 83:10:7. AC electrodes and nickel foams were assembled with potassium hydroxide (KOH) solution as the electrolyte. Electrochemical measurements were carried out with a three electrode cell using 6 M KOH as electrolyte and Hg/HgO as the reference electrode. The specific capacitance strongly depends on the pore structure; the highest specific capacitance was 179 F/g, obtained for the AC with the highest specific surface area. Additionally, different activation times, levels of heating, and chemical reagents were used to compare and determine the optimal parameters for obtaining high surface area of the activated carbon.

There is increasing interest in zirconia as a dental material due to its aesthetics, as well as the exceptionally high fracture toughness and high strength that are on offer when it is alloyed with certain oxides like yttria. In recent years, many solution based chemical synthesis methods have been reported for synthesis of zirconia, of which the sol-gel method is considered to be best. Here, we synthesize zirconia by a sol gel assisted precipitation method using either PEG or PVA as a stabilizing agent. Zirconia sol is first synthesized using the hydrothermal method. We used NaOH as the precipitating agent in this method because it is easy to remove from the final solution. Zirconium and yttrium salts are used as precursors and PEG or PVA are used as stabilizers to separate the metal ions. The resulting amorphous zirconia powder is calcined at 900˚C for 2 h to get crystallized zirconia. XRD analysis confirmed the partially stabilized zirconia synthesis in all the synthesized powders. SEM was taken to check the morphology of the powder synthesized using either PEG or PVA as a stabilizing agent and finally the transparency was calculated. The results confirmed that the powder synthesized with 10 % PVA as the stabilizing agent had highest percentage of transparency among all the synthesized powder.

Opal glass samples having different chemical compositions were synthesized and transparent glass was obtained after melting. The effects of TiO2, BaF2, and CeO2 content on the color of the opal glass were studied by observing images of the opal samples and analyzing the results via ultraviolet visible spectroscopy and color spectrometry. The aesthetic properties of the opal glass were determined by studying the transmittance of visible light in the 400 nm to 700 nm range. The basic chemical composition of opal glass was SiO2 52.9 wt%, Al2O3 12.35 wt%, Na2CO3 15.08 wt%, K2CO3 10.35 wt%, Ca3(PO)4 4.41 wt%, MgCO3 1.844 wt%, LiCO3 2.184 wt%, and TiO2 0.882 wt%. The glass samples were prepared by varying the weight percentage of TiO2, BaF2, and CeO2. The transmittance of visible light was decreased from 95 % to 75 % in the glass samples in which TiO2 content was increased from 0 to 3.882 wt%. In the blue spectrum region, as the content of TiO2 increased, the reflectance value was observed to become higher. This implies that TiO2 content induces more crystal formation and has an important effect on the optical properties of the glass. The opalescence of opal samples that contained CeO2 or BaF2 is stronger than that in the samples containing TiO2. Opal glass samples comprising TiO2 had tetragonal lattice structures; samples including CeO2 as an additive had cubic lattice structures (FCC, CeO2).

The production of functional activated carbon materials starting from inexpensive natural precursors using environmentally friendly and economically effective processes has attracted much attention in the areas of material science and technology. In particular, the use of plant biomass to produce functional carbonaceous materials has attracted a great deal of attention in various aspects. In this study the preparation of activated carbon has been attempted from rice husks via a chemical activation-assisted microwave system. The rice husks were milled via attrition milling with aluminum balls, and then carbonized under purified N2. The operational parameters including the activation agents, chemical impregnation weight ratio of the calcined rice husk to KOH (1:1, 1:2 and 1:4), microwave power heating within irradiation time (3-5 min), and the second activation process on the adsorption capability were investigated. Experimental results were investigated using XRD, FT-IR, and SEM. It was found that the BET surface area of activated carbons irrespective of the activation agent resulted in surface area. The activated carbons prepared by microwave heating with an activation process have higher surface area and larger average pore size than those prepared by activation without microwave heating when the ratio with KOH solution was the same. The activation time using microwave heating and the chemical impregnation ratio with KOH solution were varied to determine the optimal method for obtaining high surface area activated carbon (1505 m2/g).

In this study, calcium titanate (CaTiO3) gel was prepared by mixing calcium nitrate and titanium isopropoxide in 2-methoxy-ethanol. CaTiO3 gel was single-layer coated on Ti-6Al-4V using a sol-gel dip-coating technique. The coating was calcined at 750˚C in air by utilizing a very slow heating rate of 2˚C/min. The crystalline phases of the coating were characterized by x-ray diffraction using a slow scan rate of 1˚/min. The morphology of the coating was analyzed by scanning electron microscopy. The corrosion behavior of Ti-6Al-4V samples coated with CaTiO3 films were tested in an artificial saliva solution by potentiodynamic polarization and were quantified by the Tafel extrapolation method. The electrochemical parameters showed a considerable increase in the corrosion resistance for the CaTiO3-coated Ti-6Al-4V samples compared to bare substrates.