간행물

한국재료학회지 KCI 등재 SCOPUS Korean Journal of Materials Research

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권호

제18권 제1호 (2008년 1월) 10

1.
2008.01 구독 인증기관 무료, 개인회원 유료
The phase transformations and luminescent properties of Eu-doped Ca1-xSrxAl2O4 phosphors were investigated. Ca1-xSrxAl2O4:Eu2+ phosphors were synthesized by a solid-state reaction with a flux, H3BO3. A phase transformation from monoclinic CaAl2O4 to monoclinic SrAl2O4 was observed as the x values increased. A high-temperature hexagonal phase of SrAl2O4 was formed during this transformation as an intermediate phase under an H2 atmosphere due to oxygen vacancies; this did not occur in an air atmosphere. Accordingly, the emission spectra shifted from a blue region to a green region as x increased.
3,000원
2.
2008.01 구독 인증기관 무료, 개인회원 유료
Thermally evaporated 10 nm-Ni/1 nm-Au/(30 nm-poly)Si structures were fabricated in order to investigate the thermal stability of Au-inserted nickel silicide. The silicide samples underwent rapid thermal annealing at 300~1100˚C for 40 seconds. The sheet resistance was measured using a four-point probe. A scanning electron microscope and a transmission electron microscope were used to determine the cross-sectional structure and surface image. High-resolution X-ray diffraction and a scanning probe microscope were employed for the phase and surface roughness. According to sheet resistance and XRD analyses, nickel silicide with Au had no effect on widening the NiSi stabilization temperature region. Au-inserted nickel silicide on a single crystal silicon substrate showed nano-dots due to the preferred growth and a self-arranged agglomerate nano phase due to agglomeration. It was possible to tune the characteristic size of the agglomerate phase with silicidation temperatures. The nano-thick Au-insertion was shown to lead to self-arranged microstructures of nickel silicide.
4,000원
3.
2008.01 구독 인증기관 무료, 개인회원 유료
Carbon nanotube (CNT) cathodes were fabricated using nano-sized silver (Ag) powders as a bonding material between the CNTs and cathode electrodes. The effects of the powder size on the sintering behavior, the current density and emission image for CNT cathodes were investigated. As the diameter of the Ag powders decreases to 10 nm, the sintering temperature of the CNT cathode was lowered primarily due to the higher specific surface area of the Ag powders. In this study, it was demonstrated that nano-sized Ag powders can be feasibly used as a bonding material for a screen-printed CNT cathode, yielding a high current density and a uniform emission image.
4,000원
4.
2008.01 구독 인증기관 무료, 개인회원 유료
The wetting behavior of molten Fe on α-Al2O3 single crystals with three different crystallographic orientations, R(01ar12), A(11ar20), and C(0001), was investigated using the sessile drop method under a 10%H2-Ar atmosphere at 1873 K. It was found that the differences in the contact angle of the three differently oriented α-Al2O3 single crystals were not significant (within 5˚, which corresponded to the changes in the work of adhesion of 157mJ/m2) due to the surface reconstruction.
3,000원
5.
2008.01 구독 인증기관 무료, 개인회원 유료
In this study, calcium titanate (CaTiO3) gel was prepared by mixing calcium nitrate and titanium isopropoxide in 2-methoxy-ethanol. CaTiO3 gel was single-layer coated on Ti-6Al-4V using a sol-gel dip-coating technique. The coating was calcined at 750˚C in air by utilizing a very slow heating rate of 2˚C/min. The crystalline phases of the coating were characterized by x-ray diffraction using a slow scan rate of 1˚/min. The morphology of the coating was analyzed by scanning electron microscopy. The corrosion behavior of Ti-6Al-4V samples coated with CaTiO3 films were tested in an artificial saliva solution by potentiodynamic polarization and were quantified by the Tafel extrapolation method. The electrochemical parameters showed a considerable increase in the corrosion resistance for the CaTiO3-coated Ti-6Al-4V samples compared to bare substrates.
3,000원
6.
2008.01 구독 인증기관 무료, 개인회원 유료
The dc resistivity and thermoelectric power of bilayered perovskite La1.4(Sr0.2Ca1.4)Mn2O7 weremeasured as a function of the temperature. In the ferromagnetic phase, ρ(T) was accurately predicted by a0+a2T2+a4.5T4.5 with and without an applied field. At high temperatures, a significant difference between theactivation energy deduced from the electrical resistivity and thermoelectric power, a characteristic of smallpolarons, was observed. All of the experimental data can be feasibly explained on the basis of the small polaron.
4,000원
8.
2008.01 구독 인증기관 무료, 개인회원 유료
The micro-structural changes, strength characteristics, and micro-fractural behaviors at the joint interface between a Sn-4.0wt%Ag-0.5wt%Cu solder ball and UBM treated by isothermal aging are reported. From the reflow process for the joint interface, a small amount of intermetallic compound was formed. With an increase in the isothermal aging time, the type and amount of the intermetallic compound changed. The interface without an isothermal treatment showed a ductile fracture. However, with an increase in the aging time, a brittle fracture occurred on the interface due mainly to the increase in the size of the intermetallic compounds and voids. As a result, a drastic degradation in the shear strength was observed. From a microshear test by a scanning electron microscope, the generation of micro-cracks was initiated from the voids at the joint interface. They propagated along the same interface, resulting in coalescence with neighboring cracks into larger cracks. With an increase in the aging time, the generation of the micro-structural cracks was enhanced and the degree of propagation also accelerated.
4,000원
9.
2008.01 구독 인증기관 무료, 개인회원 유료
Microstructural evolution and the intermetallic compound (IMC) growth kinetics in an Au stud bump were studied via isothermal aging at 120, 150, and 180˚C for 300hrs. The AlAu4 phase was observed in an Al pad/Au stud interface, and its thickness was kept constant during the aging treatment. AuSn, AuSn2, and AuSn4 phases formed at interface between the Au stud and Sn. AuSn2, AuSn2/AuSn4, and AuSn phases dominantly grew as the aging time increased at 120˚C, 150˚C, and 180˚C, respectively, while (Au,Cu)6Sn5/Cu3Sn phases formed at Sn/Cu interface with a negligible growth rate. Kirkendall voids formed at AlAu4/Au, Au/Au-Sn IMC, and Cu3Sn/Cu interfaces and propagated continuously as the time increased. The apparent activation energy for the overall growth of the Au-Sn IMC was estimated to be 1.04 eV.
4,000원
10.
2008.01 구독 인증기관 무료, 개인회원 유료
The crystal structures and morphologies of precipitates in L10-ordered TiAl intermetallics containing nitrogen were investigated by transmission electron microscopy (TEM). Under aging at an approximate temperature of 1073 K after quenching from 1423 K, TiAl hardens appreciably due to the nitride precipitation. TEM observations revealed that needle-like precipitates, which lie only in one direction parallel to the [001] axis of the L10-TiAl matrix, appear in the matrix preferentially at the dislocations. Selected area electron diffraction (SAED) pattern analyses showed that the needle-shaped precipitate is perovskite-type Ti3AlN (P-phase). The orientation relationship between the P-phase and the L10-TiAl matrix was found to be (001)p//(001)TiAl and [010]p//[010]TiAl. By aging at higher temperatures or for longer periods at 1073 K, plate-like precipitates of Ti2AlN (H-phase) with a hexagonal structure formed on the 111 planes of the L10-TiAl matrix. The orientation relationship between the Ti2AlN and the L10-TiAl matrix is (0001)H//(111)TiAl and H//TiAl.
4,000원