The electrochemical performance for the corrosion of zinc anodes according to particle size and shape as anode in Zn/air batteries was study. We prepared five samples of Zn powder with different particle size and morphol- ogy. For analysis the particle size of theme, we measured particle size analysis (PSA). As the result, sample (e) had smaller particle size with 10.334 µm than others. For measuring the electrochemical performance of them, we measured the cyclic voltammetry and linear polarization in three electrode system (half-cell). For measuring the morphology change of them before and after cyclic voltammetry, we measured Field Emission Scanning Electron Microscope (FE- SEM). From the cyclic voltammetry, as the zinc powder had small size, we knew that it had large diffusion coefficient. From the linear polarization, as the zinc powder had small size, it was a good state with high polarization resistance as anode in Zn/air batteries. From the SEM images, the particle size had increased due to the dendrite formation after cyclic voltammetry. Therefore, the sample (e) with small size would have the best electrochemical performance between these samples.
Titanium dioxide (), which is one of the most basic materials in our daily life, plays a key role for environment purification. We synthesized nanoparticles by the hydrolysis reactions of titanium tetraisopropoxide using as a peptizing agent or as a chelating agent in the sol-gel method. The powder consisted of a rod shape or a spherical shape according to the concentration and kind of acid. The physical properties of nanoparticles were investigated with X-ray diffraction, SEM, BET analysis, and UV-Vis spectrophotometer.
We have developed a 2.5-dimensional electromagnetic particle simulation code using the particle-in-cell (PIC) method to investigate electromagnetic phenomena that occur in space plasmas. Our code is based on the leap-frog method and the centered difference method for integration and differentiation of the governing equations. We adopted the relativistic Buneman-Boris method to solve the Lorentz force equation and the Esirkepov method to calculate the current density while maintaining charge conservation. Using the developed code, we performed test simulations for electron two-stream instability and electron temperature anisotropy induced instability with the same initial parameters as used in previously reported studies. The test simulation results are almost identical with those of the previous papers.