A chemical process involves polymerization within microspheres, whereas a physical process involves the dispersion of polymer in a nonsolvent. Nano-sized monodisperse microspheres are usually prepared by chemical processes such as water-based emulsions, seed suspension polymerization, nonaqueous dispersion polymerization, and precipitation polymerizations. Polymerization was performed in a four-necked, separate-type flask equipped with a stirrer, a condenser, a nitrogen inlet, and a rubber stopper for adding the initiator with a syringe. Nitrogen was bubbled through the mixture of reagents for 1 hr. before elevating the temperature. Functional silane (3-mercaptopropyl)trimethoxysilane (MPTMS) was used for the modification of silica nanoparticles and the self-assembled monolayers obtained were characterized by X-ray photoelectron spectroscopy (XPS), laser scattering system (LSS), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), elemental analysis (EA), and thermogravimetric analysis (TGA). In addition, polymer microspheres were polymerized by radical polymerization of γ-mercaptopropyl modified silica nanoparticles (MPSN) and acrylamide monomer via precipitation polymerization; then, their characteristics were investigated. From the elemental analysis results, it can be concluded that the conversion rate of acrylamide monomer was 93% and that polyacrylamide grafted to MPSN nanospheres via the radical precipitation polymerization with AAm in ethanol solvent. The microspheres were successfully polymerized by the 'graft from' method.

(3-mercaptopropyl)trimethoxysilane (MPTMS) was used as a silylation agent, and modified silica nanoparticles were prepared by solution polymerization. 2.0 g of silica nanoparticles, 150 ml of toluene, and 20 ml of MPTMS were put into a 300 ml flask, and these mixtures were dispersed with ultrasonic vibration for 60 min. 0.2 g of hydroquinone as an inhibitor and 1 to 2 drops of 2,6-dimethylpyridine as a catalyst were added into the mixture. The mixture was then stirred with a magnetic stirrer for 8 hrs. at room temperature. After the reaction, the mixture was centrifuged for 1 hr. at 6000rpm. After precipitation, 150 ml of ethanol was added, and ultrasonic vibration was applied for 30 min. After the ultrasonic vibration, centrifugation was carried out again for 1 hr. at 6000rpm. Organo-modification of silica nanoparticles with a γ-methacryloxypropyl functional group was successfully achieved by solution polymerization in the ethanol solution. The characteristics of the γ-mercaptopropyl modified silica nanoparticles (MPSN) were examined using X-ray photoelectron spectroscopy (XPS, THERMO VG SCIENTIFIC, MultiLab 2000), a laser scattering system (LSS, TOPCON Co., GLS-1000), Fourier transform infrared spectroscopy (FTIR, JASCO INTERNATIONL CO., FT/IR-4200), scanning electron microscopy (SEM, HITACHI, S-2400), an elemental analysis (EA, Elementar, Vario macro/micro) and a thermogravimetric analysis (TGA, Perkin Elmer, TGA 7, Pyris 1). From the analysis results, the content of the methacryloxypropyl group was 0.98 mmol/g and the conversion rate of acrylamide monomer was 93%. SEM analysis results showed that the organo-modification of ultra-fine particles effectively prevented their agglomeration and improved their dispensability.

현재 국내외에서 제공되고 있는 기후변화 시나리오 자료의 경우 일단위로 제공되고 있다. 그러나 수문 설계 및 계획 시 중요한 입력자료 중 하나 는 시간단위 강우 자료로서 기후변화 시나리오에 따른 수자원 변동성을 평가하기 위해선 신뢰성 있는 상세화 기법이 필요하다. 국내외에서는 일단 위에서 일단위로 상세화 하는 기법, 또는 공간상세화 기법 연구는 다수 진행된바 있는 반면, 시간단위 상세화 기법 연구는 일단위 연구에 비해 상대 적으로 미진한 실정이다. 이러한 점에서 본 연구에서는 기후변화 시나리오에 따른 영향 평가가 가능한 자료생성을 위해 Conditional Copula 모형 을 활용하여 극치시간단위 강우량 상세화 기법을 개발하였으며, 미래 RCP 8.5 시나리오를 활용하여 연대별 극치시간강우량을 생성하였다. 생성 된 결과는 우리나라 기상청 지점별로 빈도해석을 통해 결과를 제시하였으며, 본 연구결과는 수자원 분야에서 미래 기후변화 영향을 평가하기 위한 기초자료로 활용 될 수 있을 것으로 기대된다.

To complement the general concrete, DFRCC(Ductile Fiber Reinforced Cementitious Composites) has recently received attention. An experimental study for bond slip behavior of cast-in-place DFRCC and a pultruded FRP(Fiber Reinforced Polymer) plank was used as the both permanent formwork and the tensile reinforcement for a concrete structural member is described in this paper. This study focuses on investigation of the bond capacity of sand coated interface between FRP and cast-in-place DFRCC experimentally.