Removal of dyes Reactive Blue 221, N Blue RGB and Acid Blue MTR using two different samples of activated carbon by static batch method was studied. Experimental data on optical density of solutions at different concentrations ranging from 10 to 100 mg/L and of solutions after adsorption on activated carbon samples were measured. Calibration curves were plotted and the amount of dye qe adsorbed was calculated. The data was fitted to Langmuir and Freundlich isotherms for two different carbon samples and different concentration and pH values. Constants were calculated from the slope and intercept values of the isotherms. Coefficient of correlation R2 and Standard Deviation SD were also noted. The data fitted well to the isotherms. Carbon sample C1 showed higher potential to adsorb all the three dyes. Adsorption was higher at lower concentrations. Carbon sample C2 showed better adsorption in acidic pH as compared to in alkaline pH. From the analysis of the data capacity of C1 and C2 to remove the dyes from water have been compared.
The study describes the results of batch experiments on the removal of Reactive Yellow 15 (RY15) and Reactive Black 5 (RB5) from synthetic textile wastewater onto Activated Carbon from Walnut shell (ACW). The experimental data were analyzed by the Langmuir, Freundlish, Temkin and Dubinin-Radushkevich (D-R) models of adsorption. The experiments were carried out as function of initial concentrations, pH, temperature (303-333), adsorbent dose and kinetics. The surface area and pore volumes of adsorbent were measured by BET and BJH methods. The findings confirm the surface area (BET) is 248.99 m2/g. The data fitted well with the Temkin and D-R isotherms for RY15 and RB5, respectively. The most favorable adsorption occurred in acidic pH. Pseudo-second order kinetic model were best in agreement with adsorption of RY15 and RB5 on ACW. The results indicate that walnut shell could be an alternative to more costly adsorbent currently being used for dyes removal.
The adsorption of Acid Blue 92 onto three low cost and ecofriendly biosorbents viz., cow dung ash, mango stone ash and parthenium leaves ash and commercial activated carbon have discussed in this work. The ash of all the mentioned bio-wastes was prepared in the muffle furnace at 500℃ and all the adsorbents were stored in an air thermostat. Experiments at total dye concentrations of 10~100 mg/L were carried out with a synthetic effluent prepared in the laboratory. The parameters such as pH and dye concentration were varied. Equilibrium adsorption data followed both Langmuir and Freundlich isotherms. The results indicate that cow dung ash, mango stone ash and parthenium leaves ash could be employed as low-cost alternatives to commercial activated carbon in wastewater treatment for the removal of dye.
Study on the removal of Acid Green 20 by adsorption on indigenously prepared activated carbons from cow dung, mango stone, parthenium leaves and commercial activated carbon have been carried out with an aim to obtain information on treating effluents from tanneries. The effects of various experimental parameters have been investigated by following the batch adsorption technique. Adsorption data was modeled with the Freundlich and Langmuir isotherms. Removal of Acid Green 20 was found to be favorable using Biomass ash and could be considered as alternatives to commercial activated carbon for the treatment of tannery effluents, especially for the removal of dye(s).
The ability of cow dung ash without any pretreatment to remove color from textile dyes N Blue RGB, Green B and EOSIN YWS from aqueous solution has been investigated in this work. Cow dung ash, an ecofriendly and low cost adsorbent was prepared by burning cow dung cakes in the muffle furnace at 500℃. The adsorption was achieved under different pH and adsorbate concentration. The data was fitted to simple polynomial and the isotherms similar to Langmuir and Freundlich isotherms.
The use of low cost and ecofriendly adsorbent has been investigated as an alternative to the current expensive method of removing dyes from wastewater. Cow dung cakes were collected from the nearby village which was burnt in a muffle furnace at 500℃ to obtain the required ash. This paper deals with the removal of Reactive Blue 221, Acidoll Yellow 2GNL and Olive BGL which are mainly used in textile industry, from aqueous solution by cow dung ash without any pretreatment. The adsorption was achieved under different pH, adsorbate concentration and the applicability of Langmuir and Freundlich isotherms were examined.