Plasma carbon blacks of 20~30 nm diameter were synthesized by direct decomposition of natural gas using a hybrid plasma torch system with 50 kW direct current and 4 MHz of radio frequency. The insulating rector which inside diameter of 400 mm and length of 1500 mm, respectively was kept at 300~400℃ during the preparation. The ultimate analysis of plasma carbon blacks reveals that the raw plasma carbon blacks contains a large quantity of volatile which is mainly consist of hydrogen. Therefore devolatilization of raw plasma carbon blacks were carried out at 900℃ for one hour under nitrogen atmosphere. The devolatilization leads to the decrease in electrical resistivity and surface oxygen functional groups of plasma carbon black significantly. In order to investigate the plasma carbon as a catalyst support, devolatilized plasma black at 900℃ (DPB) supported PtAu catalyst was synthesized by sodium boronhydride reduction method. Electrochemical measurements and direct formic acid fuel cell test indicated that catalytic activity of DPB supported PtAu catalyst for formic acid oxidation was similar to that of Vulcan XC-72 of commercial carbon black supported one.

The ionospheric mid-latitude trough (IMT) is the electron density depletion phenomenon in the F region during nighttime. It has been suggested that the IMT is the result of complex plasma processes coupled to the magnetosphere. In order to statistically investigate the characteristics of the IMT, we analyze topside sounding data from Alouette and ISIS satellites in 1960s and 1970s. The IMT position is almost constant for seasons and solar activities whereas the IMT depth ratio and the IMT feature are stronger and clearer in the winter hemisphere under solar minimum condition. We also calculated transition heights at which the densities of oxygen ions and hydrogen/helium ions are equal. Transition heights are generally higher in daytime and lower in nighttime, but the opposite aspects are seen in the IMT region. Utilizing the Incoherent Scatter Radar (ISR) electron temperature measurements, we find that the electron temperature in the IMT region is enhanced at night during winter. The increase of electron temperature may cause fast transport of the ionospheric plasma to the magnetosphere via ambipolar diffusion, resulting in the IMT depletion. This mechanism of the IMT may work in addition to the simply prolonged recombination of ions proposed by the traditional stagnation model.

Non-specular, vertically upward transit, fast-moving radar echoes are observed in the summer polar upper mesosphere near 90 km using 52 MHz VHF radar at Esrange, Sweden. By resolving maximum echo power movement, the unusual meteor trails propagate vertically upward with taking horizontal displacements at an initial speed of 10 km/s exponentially decreasing with increasing height from 85-89 km, lasting for 3.5 sec. Another upward transit is observed as following a downward transit echo target in about ~1 sec, lasting over 5 sec. The upward motion cannot be explained with the dynamics of penetrating meteors or by atmospheric dynamics. The observation proposes that secondary produced plasma jets occurring from meteor trail are possibly responsible for upward fast moving echoes. The long-lasting (3-5 sec), ascending meteor trails at speeds of a few 104 m/s are distinctive from any previous occurrences of meteors or upper atmospheric electrical discharges in the aspect of long-lasting upward/downward motions. This result possibly suggests a new type of meteor-trail leader discharge occurring in the summer polar upper mesosphere and lower thermosphere.

The summer polar lower thermosphere (90–100 km) has an interesting connection to meteors, adjacent to the mesopause region attaining the lowest temperature in summer. Meteors supply condensation nuclei for charged ice particles causing polar mesospheric summer echoes (PMSE). We report the observation of meteor trail with nearly horizontal transit at high speed (20–50 km/s), and at last with re-enhanced echo power followed by diffusive echoes. Changes in phase difference between radar receivers aligned in meridional and zonal directions are used to determine variations in horizontal displacements and speeds with respect to time by taking advantage of radar interferometric analysis. The actual transit of echo target is observed along the straight pathway vertically and horizontally extended as much as a distance of at least 24 km and at most 29 km. The meteor trail initially has a signature similar to ‘head echoes’, with travel speeds from 20 – 50 km/s. It subsequently transforms into a different type of echo target including specular echo and then finally the power reenhanced. The reenhancement of echo power is followed by fume-like diffusive echoes, indicating sudden release of plasma as like explosive process probably involved. We discuss a possible role of meteor-triggered secondary plasma trail, such as fireball embedded with electrical discharge that continuously varies the power and transit speed.