The 300 concrete silo systems installed and operated at the site of Wolsong nuclear power plant (NPP) have been storing CANDU spent nuclear fuel (SNF) under dry conditions since 1992. The dry storage system must be operated safely until SNF is delivered to an interim storage facility or final repository located outside the NPP in accordance with the SNF management policy of the country. The silo dry storage system consists of a concrete structure, liner steel plate in the inner cavity, and fuel basket. Because the components of the silo system are exposed to high energy radiation owing to the high radioactivity of SNF inside, the effects of irradiation during long-term storage must be analyzed. To this end, material specimens of each component were manufactured and subjected to irradiation and strength tests, and mechanical characteristics before and after irradiation were examined. Notably, the mechanical characteristics of the main components of the silo system were affected by irradiation during the storage of spent fuel. The test results will be used to evaluate the long-term behavior of silo systems in the future.

PWR spent nuclear fuel generally showed an oxide film thickness of 100 um or more with a combustion rate of 45 MWD/MTU or higher, while CANDU spent nuclear fuel with an average combustion rate of about 7.8 MWD/MTU had few issues related to hydride corrosion. Even based on the actual power plant data, it is known that the thickness of the oxide film is 10 μm or less on the surface of the coating tube, and brittleness caused by hydride is shown from the thickness of the oxide film of about 80 μm, so it is not worth considering. However, since corrosion may be accelerated by lithium ions, lithium ions may be said to be a very important factor in controlling the hydro-chemical environment of heavy water. Lithium has a negative effect on the corrosion of zirconium alloys. However, since local below 5 ppb to prevent corrosion. maintained at a concentration between 0.35 and 0.55 ppm. Hydrogen is known to have a positive effect by suppressing radioactive decomposition of the coolant and suppressing cracks in nickelbased alloys. However, too much hydrogen can produce hydride in a pressure tube composed of Zr-2.5Nb, so DH (Disolved Hydrogen) maintains the range of 0.27–0.90 ppm. pH and conductivity are completely determined by lithium ions, and DH can be completely removed below 5 ppb to prevent corrosion. Therefore, for cladding corrosion simulation of the CANDU spent nuclear fuel, a hydrochemical of the equipment, not 310°C, and 14 uS·Cm−1 is targeted as conditions for corrosion acceleration. In addition, for acceleration, the temperature was set to 345°C (margin 10°C), which is the maximum accommodation range of the equipment, not 310°C.