Today’s fast developed corporate environment requires highly professional employees, and organizational structure becomes simplified and horizontal. So, individuals’ change-oriented organizational citizen behavior(C-OCB) and innovative work behavior(IWB) are considered as important factors to improve the organizational achievement. The charismatic leadership in organization becomes very necessary. The study showed the charismatic leadership, affective commitment can make organization members achieve the performance and innovation beyond the expection, and which effectively to reform the circumstance in the corporate and increase the effectiveness of the organization and its members. In addition, this research is to empirically investigate the impacts of charismatic leadership on change-oriented organizational citizen behavior and innovative work behavior. Moreover, the mediating role of affective commitment is also measured in present research. The relationship of variances were tested using SPSS, AMOS, and Bootstrapping. In conclusion, the results of the study have indicated that the charismatic leadership as an independent variable have significantly influence on both innovative work behavior and change-oriented organizational citizen behavior which as dependent variable. Also, based on the recent research, the affective commitment plays a mediated role in the relationship between the charismatic leadership and change-oriented organizational citizen, innovative work behavior. Finally, according to the results, some practical recommendations to develop the innovative work behavior for Chinese organizational members were suggested.