Zirconia nanoparticles were widely used as filler in order to get high refractive index layer. However, dispersion of nanoparticles is difficult due to their agglomeration in solvent. In this study, the dispersibility of the zirconia suspension is promoted by controlling the steric hindrance and electrostatic interactions through the adsorption of PEI according to alkali treatment time. Also, to induce improved dispersibility on suspension, we changed the dispersion conditions variously and fabricated an ink formulation method for the coating layer. Zirconia suspension was characterized by dynamic light scattering (DLS), Zeta potential measurement, Transmission Electron Microscope (TEM) and FT-IR. We were able to confirm that good dispersion of zirconia suspension by alkali treatment and PEI led to high refractive index.

In order to examine the pre-treatment effect of crab shell on Pb2+ removal by crab shell in aqueous solution, acid and alkali pre-treated crab shell were used. Electron microscopy techniques such as TEM (transmission electron microscopy) and SEM (scanning electron microscopy), and EDX (energy dispersive X-ray) and FTIR (Fourier transform infrared) spectrometry techniques were used to investigate the process of Pb2+ removal by acid and alkali pre-treated crab shell. The Pb2+ removal by acid pre-treated crab shell was much lower than that by untreated crab shell because of the decrease of CaCO3 from the crab shell. However, the Pb2+ removal by alkali pre-treated crab shell increased compared to that by untreated crab shell. The results were confirmed by TEM, SEM, EDX and FTIR.