The aim of this study is to consider the effect hydrogen on dezincification behavior of Cu-Zn alloys. The investigations include microstructural observations with scanning electron microscope and chemical composition analysis with energy dispersive spectrometer. The dezincification layer was found to occur in high pressure hydrogen atmosphere, not in air atmosphere. In addition, the layers penetrated into the inner side along the grain boundaries in the case of hydrogen condition. The shape of the dezincification layers was porous because of Zn dissolution from the α or β phase. In the case of stress corrosion cracks formed in the Cu-Zn microstructure, the dezincification phenomenon with porous voids was also accompanied by grain boundary cracking.

수왕광상은 중생대 백악기 중기의 반상화강암이나 선캄브리아기의 소백산 편마암 복합체에 발달한 열극을 충진한 석영맥에서 산출된다. 광물 공생군에 대한 연구 결과 광화작용은 4차례에 걸쳐 일어났다. 섬아연석은 광화작용이 진행되는 동안 광화 I, II, III기에 각각 정출하였다. 현미경 관찰과 전자현미분석 결과 섬아연석에서 나타나는 황동석 점적과 황동석 병변은 광화 III기 초에 열수용액의 교대작용에 의하여 생성되었을 것으로 생각된다. 황동석 병변의 생성과정은 아래와 같다. (1) Fe가 풍부한 용액이 Fe가 결핍된 섬아연석의 가장자리나 틈을 통해 Fe부화 (2)광화 II기에 Fe가 결핍된 섬아연석에 황동석 점적을 형성하고 Cu를 함유한 용액에 의해 황동석 점적 주변의 섬아연석에 Fe 감소 (3)광화 III기 초에 황동석 병변을 형성하였다.

Ceramic pigments were developed by using 4 kinds of Brass scraps. Each Brass scraps were mixed with same weight-ratio of Husk ash, and fine-ground by Rotate ring mill(RRG-120, Armstech industrial. co. Ltd, Korea) after firing at 900℃, 1000℃ and 1100℃. As a result, analysis of particle size of synthetic pigments by particle size analyser, they are 3μm as average. The resulting pigments were characterized by using XRD, FT-IR, SEM Structure of the crystals are Zn2SiO4,, and ZnO, Cu2O, CuO, and cristobalite are existed and particles' shape are plate or needle. As a result of analysis of chemical composition by XRF, synthetic pigments have high SiO2 and CuO content and have SnO2, ZnO and NiO, too. 1wt%, 3wt% and 5wt% pigments were added in each lime glaze, lime-barium glaze and lime-magnesia glaze, and fired at oxidation and reducing atmosphere to figure hue in glazes out. As a result of analysis of color, chroma and brightness by UV, colors of glazes fired at oxidation atmosphere turned into green from sky blue, and colors of glazes fired at reducing atmosphere turned into pink and red.

황동 개재물이 있는 Al 정사각판의 고유진동수는 혼합법칙을 이용하여 해석되었다. 혼합법칙에 의한 고유진동수는 개재물의 크기에 따른 유효 내평면 파동속도와 무차원 진동수 매개변수와의 곱으로 이루어진다. 해석모델은 외팔형, 2변 고정-2변 자유형, 3변 고정-1변 자유형 및 4변 고정형의 황동 개재물이 있는 4가지의 Al판이다. 자유단이 1개 이상 존재하는 경계조건에서 개재물이 판의 중앙에 위치하였을 때 개재물에 대한 판 전체의 면적비가 1/9 이하이면 혼합법칙 및 유한요소 해석에 의한 고유진동수는 10% 이내로 잘 일치하였다 4변 고정형 경계조건을 제외하고 3가지 경계조건에서 개재물이 판중앙에 있을 경우 개재물의 크기가 커짐에 따라 개재물이 있는 판의 고유진동수는 낮아짐을 알았다. 또한 개재물의 밀도가 판의 밀도보다 작을 때, 개재물 크기가 커짐에 따라 개재물이 있는 판의 고유진동수는 높아진다.

Al-brass is usually used as the tube material of vessel's heat exchanger for seawater cooling system because it has high thermal conductivity and good mechanical properties and high corrosion resistance due to cuprous oxide (Cu20) layer against seawater. However, Al-brass tubes of heat exchanger for vessel at the actual environment is reported that local corrosion such as stress corrosion cracking occurred by synergism effect between mechanical factor and corrosion environment In this paper, the effect of corrosion environment on the stress corrosion cracking of Al-brass in various NH4OH of 3.5% NaCl solution, under flow by constant displacement tester. Based on the test results, the behavior of polarization, stress corrosion crack propagation and dezincification phenomenon of Al-brass are investigated. The main results are as follows：(1) Increasing range of potential from open circuit potential to repassivation gets lower, as the contain rate of NH4OH gets higher. (2) As contain rate of NH4OH gets higher, SCC of Al-brass is become activation but the protection film(Cu20) of Al-brass is created in 3.5% NaCl solution. (3) According as content of NH4OH increases in 3.5% NaCl solution, the dezincifiction area is spread. It is concluded that dezincification occurred by localized preferential anodic dissolution at stress focusing region.