PURPOSES : The purpose of this study was to evaluate the performance of a titanium dioxide (TiO2) asphalt surface treatment agent for reducing NOx on the roadside at laboratory and full scales. METHODS : To verify the NOx reduction performance of TiO2 and silicon-based resin-applied surface treatment agents at the lab scale, a bed flow photo reactor test (ISO standard) and a mixed tank photo reactor test designed to apply real-scale construction materials were conducted. Subsequently, the full-scale NOx reduction performance was verified using a full-scale demonstration facility, and the field construction capability of the TiO2 asphalt surface treatment agent was verified through actual road site application. RESULTS : The bed flow photoreactor and mixed tank photoreactor methods showed the same trend in the NOx removal performance. Evaluation of the NOx removal performance of the TiO2 surface treatment agent revealed that the NO removal rate was approximately 13% at the laboratory scale and 15% at full scale. CONCLUSIONS : Through this study, it was determined that the asphalt surface treatment agent applied with TiO2 will have a sufficient NOx reduction effect in an actual road site. In the future, it will be necessary to analyze the continuity of the effect according to traffic volume through continuous monitoring in the field.