A compacted bentonite buffer is a major component of engineered barrier systems, which are designed for the disposal of high-level radioactive waste. In most countries, the target temperature required to maintain safe functioning is below 100°C. If the target temperature of the compacted bentonite buffer can be increased above 100°C, the disposal area can be dramatically reduced. To increase the target temperature of the buffer, it is necessary to investigate its properties at temperatures above 100°C. Although some studies have investigated thermal-hydraulic properties above 100°C, few have evaluated the water suction of compacted bentonite. This study addresses that knowledge gap by evaluating the water suction variation for compacted Korean bentonite in the 25–150°C range, with initial saturations of 0 and 0.22 under constant saturation conditions. We found that water suction decreased by 5–20% for a temperature increase of 100–150°C.

In the majority of countries, the upper limit of buffer temperature in a repository is set to below 100℃ due to the possible illitization. This smectite-to-illite transformation is expected to be detrimental to the swelling functions of the buffer. However, if the upper limit is increased while preventing illitization, the disposal density and cost-effectiveness for the repository will dramatically increase. Thus, understanding the characteristics and creating a database related to the buffer under the elevated temperature conditions is crucial. In this study, a strategy to investigate the bentonite found in Korea under the elevated temperatures from a mineral transformation and radionuclides retardation perspective was proposed. Certain long-term hydrothermal reactions generated the bentonite samples that were utilized for the investigation of their mineral transformation and radionuclide retardation characteristics. The bentonite samples are expected to be studied using in-situ synchrotron-based X-Ray Diffraction (XRD) technique to determine the smectite-to-illite transformation. Simultaneously, the ‘high-temperature and high-pressure mineral alteration measurement system’ based on the Diamond Anvil Cell (DAC) will control and provide the elevated temperature and pressure conditions during the measurements. The kinetic models, including the Huang and Cuadros model, are expected to predict the time and manner in which the illitization will become detrimental to the performance and safety of the repository. The sorption reactions planned for the bentonite samples to evaluate the effects on retardation will provide the information required to expand the current knowledge of repository optimization.