Biogas has been used to remove water content and hydrogen sulfide (H2S). Removing water requires a low temperature process; thus, our study investigated removing H2S under high pressure and low temperature. Several experiments were conducted to investigate removal of H2S from a biogas stream by optimizing chemical absorption and the chemical reaction with a Fe/EDTA solution. The roles of Fe/EDTA were studied to enhance removal efficiency of H2S due to oxidization by Fe+3/EDTA. The objective of this study was to explore the feasibility of enhancing toxic gas treatment in a biogas facility. A biogas purification strategy affords many advantages. For example, the process can be performed under mild environmental conditions and at low temperature, and it removes H2S selectively. As the Fe-EDTA concentration increased, the H2S conversion rate increased because the Fe-EDTA complex was highly stable. The optimal pH to stabilize the chemical complex during oxidation of H2S was 9.0.
Several experiments have done to investigate the removal of hydrogen sulfide(H2S) synthetic gas from biogas streams by means of chemical absorption and chemical reaction with 0.1 M – 1 M Fe/EDTA solution. The hydrogen sulfide of biogas was bubbled through an gas-lift column with Fe/EDTA resulting in the formation of sulfur particles. Wide range of optimal operating conditions were tested for both Fe/EDTA solution and the biogas, and the optimal ratio of Fe/EDTA concentration for efficient removal of hydrogen sulfide was found. The roles of Fe/EDTA were studied to enhance the removal efficiency of hydrogen sulfide because of oxidizing by Fe+3/EDTA. The motivation of this investigation is first to explore the feasibility of enhancing the toxic gas treatment in the biogas facility. The biogas purification strategy affords many advantages. For instance, the process can be performed under mild environmental conditions and at low temperature, and it removes hydrogen sulfide selectively. The end product of separation is elemental sulfur, which is a stable material that can be easily disposed of with minor potential for further pollution. The process to address over 90% removal efficiency of hydrogen sulfide does offer considerable advantages unrealized.