The gas sensor sensitivity value of three methods (simple application method, vaporization method, and chamber method) were compared in order to establish a method for the measurement of liquid odor substances. In order to select the representative sensors from among the 16 sensors constituting the gas sensor array, cluster analysis, regression analysis, and correlation analysis were performed. Sensors with excellent correlation in terms of reactivity were selected as representative sensors of each measurement method. As a result, it was shown that the reactivity and the correlation increased in the order of simple application method < vaporization method < chamber method. Through a variance analysis using the sensitivity values of selected representative sensors, it was shown that the simple application method had statistical significance at the level of 99.9% (p<0.001) in three of the representative sensors in four clustering groups. The vaporization method and the chamber method showed statistical significance at a level of 99.9% (p<0.001) for all representative sensors in each clustering group. If the reactivity were improved by controlling the sensitivity of the sensor, the simple application method and vaporization method could also be used as a method of measuring the liquid material with gas sensor array.
A novel electrode for an NO gas sensor was fabricated from electrospun polyacrylonitrile fibers by thermal treatment to obtain carbon fibers followed by chemical activation to enhance the activity of gas adsorption sites. The activation process improved the porous structure, increasing the specific surface area and allowing for efficient gas adsorption. The gas sensing ability and response time were improved by the increased surface area and micropore fraction. High performance gas sensing was then demonstrated by following a proposed mechanism based on the activation effects. Initially, the pore structure developed by activation significantly increased the amount of adsorbed gas, as shown by the high sensitivity of the gas sensor. Additionally, the increased micropore fraction enabled a rapid sensor response time due to improve the adsorption speed. Overall, the sensitivity for NO gas was improved approximately six-fold, and the response time was reduced by approximately 83% due to the effects of chemical activation.
nanopowders with anatase structure were firstly prepared by controlling the pH value of a precursor solution without any heat-treatment at room temperature. The prepared nanopowders were hydrothermally treated in 10M NaOH solution at . Then, the samples were washed in DI water or 0.1M HCl. The nanotubes were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). The gas sensitivity of nanotubes for toluene gas was also investigated. The results show that nanotubes can be prepared by hydrothermal treatment. The morphology of nanotubes prepared by 0.1M HCl washing is destroyed to some extent. nanotubes with DI water washing show better sensitivity than that with 0.1M HCl washing.
ZnO thin films were prepared on a glass substrate by radio frequency (RF) magnetron sputtering without intentional substrate heating and then surfaces of the ZnO films were irradiated with intense electrons in vacuum condition to investigate the effect of electron bombardment on crystallization, surface roughness, morphology and hydrogen gas sensitivity. In XRD pattern, as deposited ZnO films show a higher ZnO (002) peak intensity. However, the peak intensity for ZnO (002) is decreased with increase of electron bombarding energy. Atomic force microscope images show that surface morphology is also dependent on electron bombarding energy. The surface roughness increases due to intense electron bombardment as high as 2.7 nm. The observed optical transmittance means that the films irradiated with intense electron beams at 900 eV show lower transmittance than the others due to their rough surfaces. In addition, ZnO films irradiated by the electron beam at 900 eV show higher hydrogen gas sensitivity than the films that were electron beam irradiated at 450 eV. From XRD pattern and atomic force microscope observations, it is supposed that intense electron bombardment promotes a rough surface due to the intense bombardments and increased gas sensitivity of ZnO films for hydrogen gas. These results suggest that ZnO films irradiated with intense electron beams are promising for practical high performance hydrogen gas sensors.
Sn doped In2O3 (ITO) and ITO/Cu/ITO (ICI) multilayer films were prepared on glass substrates with a reactive radiofrequency (RF) magnetron sputter without intentional substrate heating, and then the influence of the Cu interlayer on themethanol gas sensitivity of the ICI films were considered. Although both ITO and ICI film sensors had the same thicknessof 100nm, the ICI sensors had a sandwich structure of ITO 50nm/Cu 5nm/ITO 45nm. The ICI films showed a ten timeshigher carrier density than that of the pure ITO films. However, the Cu interlayer may also have caused the decrement of carriermobility because the interfaces between the ITO and Cu interlayer acted as a barrier to carrier movement. Although the ICIfilms had two times a lower mobility than that of the pure ITO films, the ICI films had a higher conductivity of 3.6·10-4Ωcmdue to a higher carrier density. The changes in the sensitivity of the film sensors caused by methanol gas ranging from 50 to500ppm were measured at room temperature. The ICI sensors showed a higher gas sensitivity than that of the ITO single layersensors. Finally, it can be concluded that the ICI film sensors have the potential to be used as improved methanol gas sensors.
Hydroxide법으로 α-주산산(stannic acid)을 만든후, 하고온도를 500˚C~1100˚C로 조정하여 일차입자(Crystallite)크기가 8-54nm인 SnO2 분말을 제작하였다. 분말의 입자(drystalite)클기에 따른 분말특성와 H2, CO가스(0.5v/o)에 대한 감응성 미치공기중에서의 저상변화특성에 미치는 영향을 조사하였다. 입자크기가 감소함에 따라, 분말의 FTIR 흡습특성은 증가하였으나, 격자상수는 일정하였다. 후막소자에서, H2가스에 대해 최대감도를 나타내는 온도와 공기중에서 최소저항을 나타내는 온도는 입자크기가 미세해짐에 따라 점차 낮아졌다. 최소저항점과 최대감도점의 온도저하를 산소흡착종의 활성화에너지의 감소라고 유추하였고, 이러한 에너지의 감소가 미세입자에 의한 감도향상요인 중의 한가지라고 제의하였다.