Necessity of novel energy storage devices extensively increased due to consumption of high power in various devices. To address the issues, in this report, we are addressing with a composite Iron Sulfide/reduced Graphene Oxide ( Fe3S4/rGO) synthesized using the standard solvothermal method. X-ray diffraction and Field Emission Scanning Electron Microscope analysis results confirmed that Face-Centered cubic crystal structure of Fe3S4 and rGO’s surface is decorated with a mean diameter of < 50 nm Fe3S4 respectively. Transmission Electron Microscopy images show further evidence that dispersed Fe3S4 on the rGO surface. Fe3S4/ rGO exhibits specific capacitance of 560 F/g than its individual counterparts ( Fe3S4 = 200 F/g and rGO = 145 F/g) at 1 A/g of current density and maximum cyclic stability of 91% capacitance retention after 2000 cycles that may be the influence of synergy between the composite materials.
This study was carried out to examine the characteristics of hydrogen sulfide adsorption using an iron hydroxide-based adsorbent. The prepared adsorbent was discussed with regard to its adsorption capacity and analyzed via surface analysis methods to illustrate the physical characteristics of hydrogen sulfide adsorption. As the drying temperature increased, the adsorption capacity of the adsorbent decreased from 29.15wt% to 22.73wt%. The adsorption capacity was decreased as the space velocity increased and showed an adsorption capacity of about 3.65 at 3,157.6 h−1. The effect of sulfur dioxide was to decrease the adsorption capacity from 29.15wt% to 27.94wt%. The adsorbent exhibited the amorphous type in its physical appearance based on XRD and EDS analysis.
The purpose of the present study is to examine characteristics of hydrogen sulfide adsorption using iron-activated carbon composite adsorbents prepared by ferric nitrate and ferric chloride. Prepared adsorbents were discussed on H2S adsorption capacity. Also, adsorbents were analyzed by surface analysis methods for illustrating the physical characteristics of H2S adsorption. The breakthrough tests of H2S were conducted at 3,333 ppm of inlet concentration, demonstrating that the adsorption capacity for iron-activated carbon composite adsorbents was in order of FC_AC (Ferric chloride_Activated carbon), FN_AC (Ferric nitrate_Activated carbon), FC (Ferric chloride) and FN (Ferric nitrate). Adsorption capacity of FC was 0.06 g/g, whereas FC_AC showed the highest capacity of 0.171 g/g. All adsorbents exhibited the amorphous type in physical appearance based on XRD analysis and high Fe content based on EDS analysis. The surface areas of composites were increased by adding activated carbon, exhibiting better adsorption capacity.