Leachate from municipal landfill site is known to be hard to treat because it commonly contains various toxic material and heavy metals. In addition, portions of biodegradable organic substances in leachate are decreasing in the course of wastes stabilization, which is one of the critical reason for inefficient biological treatment at the end stage of landfill site operation. So this study was conducted to examine the feasibility of municipal landfill leachate pretreatment using electrolysis. The optimum electrode combination was made. The optimum electrode combination was found to be lead and graphite.