In this study, the combustion characteristics of low calorific gas (LCG) fuels are investigated by numerical simulation. PREMIXED code is used to predict the flame structure and NO emission with two mechanisms, which are GRI 3.0 and USC II chemical reaction mechanisms for CH4 and LCG 8000 and LCG 6000, respectively. Also, elementary reactions related with production and destruction for OH radical are studied because OH radical is dominant for burning velocity and NO emission. As results, the production and the destruction of OH radical for CH4 and LCG 8000 using GRI 3.0 are dominated by reactions of No. 4, No. 2 and No. 3 and by No. 5, No. 3 and No. 7, respectively. For LCG 6000 using USC II, reactions of No. 3, No. 4 and No. 11 and of No. 7, No. 8 and No. 12 dominates to the production and the destruction, respectively. In addition, NO emissions for LCG gas fuel are generated by thermal NO because the flame temperatures are over 1800 K.