Sulfide concentrations critically affect worker safety and the integrities of underground facilities, such as deep geological repositories for spent nuclear fuel. Sulfide is highly sensitive to oxygen, which can oxidize sulfide to sulfate. This can hinder precise measurement of the sulfide concentration. Hence, a literature review was conducted, which revealed that two methods are commonly used: the methylene blue and sulfide ion-selective electrode (ISE) methods. Inductively coupled plasma optical emission spectroscopy (ICP-OES) was used for comparison with the two methods. The sulfide ISE method was found to be superior as it yielded results with a higher degree of accuracy and involved fewer procedures for quantification of the sulfide concentration in solution. ICP-OES results can be distorted significantly when sulfide is present in solution owing to the formation of H2S gas in the ICP-OES nebulizer. Therefore, the ICP-OES must be used with caution when quantifying underground water to prevent any distortion in the measured results. The results also suggest important measures to avoid problems when using ICP-OES for site selection. Furthermore, the sulfide ISE method is useful in determining sulfide concentrations in the field to predict the lifetime of disposal canisters of spent nuclear fuel in deep geological repositories and other industries.

In East Asia, the long-range transport of dust storms originating from Mongolia and northern China affects airborne dust loadings over downwind areas in the southern Korean Peninsula. Since 1997, dust loading cases caused by dust storms have been observed using the thresholds of total suspended particles (TSP, ≥250 μg m−3 hr−1 ) and particulate matter less than 10 μg (PM10, ≥190 μg m−3 hr−1 ) in the central-southern Korean Peninsula. There were two dust loading cases that exceeded these thresholds in 2016 and three in 2017, which reflects the downward trend of the last twenty-one years in the central-southern Korean Peninsula. Furthermore, five other dust loading cases with mass concentrations lower than the thresholds were observed from 2016 to 2017. In the moderate dust loading cases exceeding the thresholds, a descending motion of cut-off lows below 45 o N and a southward trough at 500 hPa gpm isopleths intensified at the western ridge, and largely extended the surface high-pressure system over southeast China. Airborne dust loadings following pronounced north-westerlies in the forward side of the high-pressure system were transported to the surface of the central-southern Korean Peninsula. However, in slight dust loading cases lower than the thresholds, the restricted descending motion of cut-off lows over 45 o N and the southwestward trough at 500 hPa gpm isopleths intensified the zonal flow over the Korean Peninsula. Surface high- and low-pressure systems moved eastward from the source compared to moderate dust loading cases. Due to the zonal movement of dust storms traversing eastern China, slight dust loading cases were observed with relatively higher ratios of PM2.5/TSP and carbon monoxide (CO) in the central-southern Korean Peninsula.

본 연구에서는 2006년부터 2008년까지 3년간 봄철에 PM10과 PM2.5를 채취하여 질량농도와 금속원소의 화학적 특성, 기상인자와의 관계 분석, 황사 및 비황사시의 미세먼지 특성 그리고 이동경로에 따른 농도의 특성을 고찰하였다. 연구기간동안의 PM10, PM2.5, PM10-2.5평균농도는 각각 126.2±89.8, 85.5±41.6, 40.7±54.9μg/m3이었으며 PM2.5/PM10 및 PM10-2.5/PM2.5 비는 각각 0.70, 0.48이었다. 우리나라의 북서쪽인 북경을 포함한 지역과 서쪽인 상해를 포함한 지역에서 공기덩어리가 이류 할 때 가장 높은 미세먼지농도를 나타내었다.

This study was performed to research ozone concentration related to airmass thunderstorm using 12 years meteorological data(1990～2001) at Busan. The occurrence frequency of thunderstorm during 12 years was 156 days(annual mean 13days). The airmass thunderstorm frequency was 14 days, most of those occurrence at summertime(59%). In case August 4, 1996, increase of ozone concentration was simultaneous with the decrease of temperature and increase of relative humidity. In case July 23, 1997, ozone concentration of western site at Busan increased, while its of eastern site decreased as airmass thunderstorm occurred(about 1500LST). It is supposed that these ozone increases are the effect of ozone rich air that is brought down by cumulus downdrafts from height levels where the ozone mixing ratio is larger. Thunderstorms can cause downward transport of ozone from the reservoir layer in the upper troposphere into planetary boundary layer(PBL). This complex interaction of source and sink processes can result in large variability for vertical and horizontal ozone distributions. Thus a variety of meteorological processes can act to enhance vertical mixing between the earth's surface and the atmospheric in the manner described for thunderstorm.