The paper investigates the possibility to avoid extrinsic embrittlement of , also increasing the high temperature strength, by alloying with both Fe - of a high strengthening effect and Cr - able to remove a part of diffused oxygen along the grain boundaries. As Cr homogenization in is difficult because of its low diffusion coefficient, for its improving a mechanical alloying (MA) step before the compound synthesis by Self-propagating High-temperature Synthesis (SHS) was adopted. The obtained better homogenization resulted in higher mechanical resistance and deformability than of the unalloyed alloys of the same composition obtained without MA step.