The buffer is installed around the disposal canister, subjected to heating due to decay heat while simultaneously experiencing expansion influenced by groundwater inflow from the surrounding rock. The engineering barrier system for deep geological disposal require the evaluation of longterm evolution based on the verification of individual component performance and the interactions among components within the disposal environment. Thus, it is crucial to identify the thermalhydro- mechanical-chemical (THMC) processes of the buffer and assess its long- and short-term stability based on these interactions. Therefore, we conducted experimental evaluations of saturationswelling, dry heating, gas transport, and mineralogical alterations that the buffer may undergo in the heated-hydration environment. We simulated a 310 mm-thick buffer material in a cylindrical form, simulating the domestic disposal system concept of KRS+ (the improved KAERI reference disposal system for spent nuclear fuel), and subjected it to the disposal environment using heating cartridges and a hydration system. To monitor the thermal-hydro-mechanical behavior within the buffer material, load cells were installed in the hydration section, and both of thermal couples and relative humidity sensors were placed at regular intervals from the heat source. After 140 days of heating and hydration, we dismantled the experimental cell and conducted post-mortem analyses of the samples. In this post-mortem analysis, we performed functions of distance from the water contents, heat source, wet density, dry density, saturation, and X-Ray diffraction analysis (XRD). The results showed that after 140 days in the heated-hydration environment, the samples exhibited a significant decrease water contents and saturation near the heat source, along with very low wet and dry densities. XRD Quantitative Analysis did not indicate mineralogical changes. The findings from this study are expected to be useful for input parameters and THMC interaction assessments for the long-term stability evaluation of buffer in deep geological disposal.